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发 送 文 章     C.I. 溶剂紫 1 （C.I. 12196）生产工艺 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <span><strong><u>C.I. </u></strong></span><strong><u><span style="font-family:宋体;">溶剂紫</span><span> 1 </span></u></strong><strong><u><span style="font-family:宋体;">（</span><span>C.I. 12196</span></u></strong><strong><u><span style="font-family:宋体;">）生产工艺</span><span><span>     </span></span></u></strong><strong><u><span style="font-size:9pt;"><span>   </span>CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">号</span></u></strong><strong><u><span style="font-size:9pt;">: [32517-38-7]</span></u></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">名</span></u></strong><strong><u><span style="font-size:9pt;">: </span></u></strong><strong><span style="font-size:9pt;"><span> </span>Cobaltate(1-), </span></strong><span style="font-size:9pt;">bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2-)-, hydrogen</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">参考文献：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">染料索引：</span><span style="font-size:9pt;">BIOS 961, 95 (</span><span style="font-size:9pt;font-family:宋体;">未收录</span><span style="font-size:9pt;">)</span><span style="font-size:9pt;font-family:宋体;">。</span><span style="font-size:9pt;">FIAT 1313,III, 135 (</span><span style="font-size:9pt;font-family:宋体;">只有简单的制法</span><span style="font-size:9pt;">)</span><span style="font-size:9pt;font-family:宋体;">。无生产工艺文献。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>                         </span></span><strong><u><span style="font-size:9pt;font-family:宋体;">柴邦坚牢紫</span></u></strong><strong><u><span style="font-size:9pt;">BE(Zaponechtviolet BE)</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">生产工艺规程</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">偶氮车间</span><span style="font-size:9pt;"><span>                     </span><strong>Ludwigshafen </strong></span><strong><span style="font-size:9pt;font-family:宋体;">厂</span></strong><strong><span style="font-size:9pt;"><span>   </span>1944</span></strong><strong><span style="font-size:9pt;font-family:宋体;">年</span></strong><strong><span style="font-size:9pt;">6</span></strong><strong><span style="font-size:9pt;font-family:宋体;">月</span></strong><strong><span style="font-size:9pt;">29</span></strong><strong><span style="font-size:9pt;font-family:宋体;">日</span></strong><strong><span style="font-size:9pt;"></span></strong> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">产品名称，学名，分子式和分子量：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">柴邦坚牢紫</span><span style="font-size:9pt;">BE = </span><span style="font-size:9pt;font-family:宋体;">重氮化的</span><span style="font-size:9pt;">5-</span><span style="font-size:9pt;font-family:宋体;">硝基</span><span style="font-size:9pt;">-2-</span><span style="font-size:9pt;font-family:宋体;">氨基苯酚与</span><span style="font-size:9pt;">2-</span><span style="font-size:9pt;font-family:宋体;">萘酚偶合，再以</span><span style="font-size:9pt;">1:2 </span><span style="font-size:9pt;font-family:宋体;">钴络合。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">结构式</span><span style="font-size:9pt;">: </span><span style="font-size:9pt;font-family:宋体;">略。</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">分子式：</span><span style="font-size:9pt;">C<sub>32</sub>H<sub>19</sub>N<sub>6</sub>O<sub>8</sub>.Co.2H<sub>2</sub>O = 710.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">化学过程：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">重氮化的</span><span style="font-size:9pt;">5-</span><span style="font-size:9pt;font-family:宋体;">硝基</span><span style="font-size:9pt;">-2-</span><span style="font-size:9pt;font-family:宋体;">氨基苯酚，在碱性溶液中与</span><span style="font-size:9pt;">2-</span><span style="font-size:9pt;font-family:宋体;">萘酚偶合，经分离，将所得单偶氮染料在醋酸液中与二氯化钴络合，再经分离的钴络合染料。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">反应方程式：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">本人有加注，可参见</span><span style="font-size:9pt;">C.I. </span><span style="font-size:9pt;font-family:宋体;">溶剂黑</span><span style="font-size:9pt;">34</span><span style="font-size:9pt;font-family:宋体;">生产工艺。<br /> <img alt="" src="http://www.陈忠源化学文库.cn//chenzhongyuan/Upload/ArticlePicture/IMG_28012016_154713.png" /></span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">原件：</span></u></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">分子式：</span><span style="font-size:9pt;">C<sub>6</sub>H<sub>6</sub>N<sub>2</sub>O<sub>3</sub> + HNO<sub>2</sub> + C<sub>10</sub>H<sub>8</sub>O + <sup>1</sup>/<sub>2</sub> CoO + <sup>1</sup>/<sub>2</sub> O – 2H<sub>2</sub>O<span>  </span></span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"><span>  </span><sup>1</sup>/<sub>2</sub> C<sub>32</sub>H<sub>19</sub>N<sub>6</sub>O<sub>8</sub>.Co.2H<sub>2</sub>O</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>       </span></span><span style="font-size:9pt;font-family:宋体;">分子量：</span><span style="font-size:9pt;"><span>  </span>154<span>   </span>+<span>  </span>47<span>  </span>+<span>  </span>144<span>  </span>+<span>  </span>38<span>  </span>+<span>  </span>8<span>  </span>-<span>  </span>36<span>   </span></span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"><span>  </span><sup>1</sup>/<sub>2</sub> 710</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">理论投得量与每百公斤投得量：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>               </span>92(100%) + 86(100%) + 23(100%)<span>  </span></span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 213(100%)</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>              </span>100(100%) + 93(100%) + 25(100%)<span>  </span></span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 231(100%)</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">实际投得量与每百公斤投得量：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>               </span>92(100%) + 90(100%) + 23(100%)<span>  </span></span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 200 </span><span style="font-size:9pt;font-family:宋体;">标准品</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>              </span>100(100%) + 98(100%) + 25(100%)<span>  </span></span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 217 </span><span style="font-size:9pt;font-family:宋体;">标准品</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">标准品纯染料含量</span><span style="font-size:9pt;">95%</span><span style="font-size:9pt;font-family:宋体;">。收率：</span><span style="font-size:9pt;">89%</span><span style="font-size:9pt;font-family:宋体;">。纯染料含量通过与标准品染色比较得出。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产周期与日产量：</span></u></strong><span style="font-size:9pt;"><span>  </span>3</span><span style="font-size:9pt;font-family:宋体;">天（不包括烘干）。</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">译注：无三班倒。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">A.<span>  </span></span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">设备：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">重氮偶合用：略。</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">钴络合用：略。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">B.<span>  </span></span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">操作步骤：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">1. </span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">重氮化，偶合：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">（投量</span><span style="font-size:9pt;">0.6</span><span style="font-size:9pt;font-family:宋体;">公斤分子）</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">92</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">100% 5-</span><span style="font-size:9pt;font-family:宋体;">硝基</span><span style="font-size:9pt;">-2-</span><span style="font-size:9pt;font-family:宋体;">氨基苯酚（分子量</span><span style="font-size:9pt;">154</span><span style="font-size:9pt;font-family:宋体;">），于</span><span style="font-size:9pt;">600</span><span style="font-size:9pt;font-family:宋体;">升</span><span style="font-size:9pt;">15<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">温水中，加入</span><span style="font-size:9pt;">150</span><span style="font-size:9pt;font-family:宋体;">升盐酸搅拌，然后在</span><sup><span style="font-size:9pt;">3</span></sup><span style="font-size:9pt;">/<sub>4</sub> </span><span style="font-size:9pt;font-family:宋体;">小时内加入</span><span style="font-size:9pt;">180</span><span style="font-size:9pt;font-family:宋体;">升</span><span style="font-size:9pt;">23%</span><span style="font-size:9pt;font-family:宋体;">亚硝酸钠溶液，重氮化温度</span><span style="font-size:9pt;">20-25<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">加毕，搅拌反应</span><span style="font-size:9pt;">2</span><span style="font-size:9pt;font-family:宋体;">小时，体积</span><span style="font-size:9pt;">1400</span><span style="font-size:9pt;font-family:宋体;">升。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">将重氮液在</span><span style="font-size:9pt;">10</span><span style="font-size:9pt;font-family:宋体;">分钟内加入到下列偶合液内。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">90</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">100% 2-</span><span style="font-size:9pt;font-family:宋体;">萘酚（分子量</span><span style="font-size:9pt;">144</span><span style="font-size:9pt;font-family:宋体;">），于</span><span style="font-size:9pt;">700</span><span style="font-size:9pt;font-family:宋体;">升</span><span style="font-size:9pt;">25<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">热水中，加</span><span style="font-size:9pt;">72</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">50%</span><span style="font-size:9pt;font-family:宋体;">液碱溶解，并加入</span><span style="font-size:9pt;">22</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">100%</span><span style="font-size:9pt;font-family:宋体;">工业碳酸氢钠，加冰冷至</span><span style="font-size:9pt;">10<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">加水至体积</span><span style="font-size:9pt;">1300</span><span style="font-size:9pt;font-family:宋体;">升。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">偶合很快完成。<strong><u>取样</u></strong></span><strong><u><span style="font-size:9pt;">1.</span></u></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">测反重氮体。<strong><u>取样</u></strong></span><strong><u><span style="font-size:9pt;">2.</span></u></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">搅拌</span><sup><span style="font-size:9pt;">1</span></sup><span style="font-size:9pt;">/<sub>4</sub> </span><span style="font-size:9pt;font-family:宋体;">小时后，偶合液用</span><span style="font-size:9pt;">240</span><span style="font-size:9pt;font-family:宋体;">升盐酸酸化到刚果红显酸性，加热到</span><span style="font-size:9pt;">40<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">，在此温度保持</span><sup><span style="font-size:9pt;">3</span></sup><span style="font-size:9pt;">/<sub>4</sub></span><span style="font-size:9pt;font-family:宋体;">小时，然后在</span><sup><span style="font-size:9pt;">1</span></sup><span style="font-size:9pt;">/<sub>2</sub></span><span style="font-size:9pt;font-family:宋体;">小时内，再加入用</span><span style="font-size:9pt;">300</span><span style="font-size:9pt;font-family:宋体;">升水稀释的</span><span style="font-size:9pt;">50</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">50%</span><span style="font-size:9pt;font-family:宋体;">液碱，使溶液显碱性，到不再有反重氮体检出为止，偶合完毕，加入</span><span style="font-size:9pt;">2000</span><span style="font-size:9pt;font-family:宋体;">升水稀释，体积</span><span style="font-size:9pt;">5500</span><span style="font-size:9pt;font-family:宋体;">升，压滤。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">压滤需一台</span><span style="font-size:9pt;">28</span><span style="font-size:9pt;font-family:宋体;">框压滤机，</span><span style="font-size:9pt;">120 x 120 x 3.5 cm.<span>   </span></span><span style="font-size:9pt;font-family:宋体;">压滤时间：</span><span style="font-size:9pt;">8</span><span style="font-size:9pt;font-family:宋体;">小时。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">得滤饼量：约</span><span style="font-size:9pt;">750</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;"> = 175</span><span style="font-size:9pt;font-family:宋体;">公斤钴络合紫</span><span style="font-size:9pt;">BE</span><span style="font-size:9pt;font-family:宋体;">标准品。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">2. </span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">钴络合：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">上述偶合液滤饼用</span><span style="font-size:9pt;">1500</span><span style="font-size:9pt;font-family:宋体;">升水打浆，加入约</span><span style="font-size:9pt;">15</span><span style="font-size:9pt;font-family:宋体;">公斤醋酸到石蕊试纸显酸性，然后加入由</span><span style="font-size:9pt;">72</span><span style="font-size:9pt;font-family:宋体;">公斤结晶二氯化钴（含钴</span><span style="font-size:9pt;">24%</span><span style="font-size:9pt;font-family:宋体;">）用</span><span style="font-size:9pt;">300</span><span style="font-size:9pt;font-family:宋体;">升水溶解的钴化液，再加入</span><span style="font-size:9pt;">165</span><span style="font-size:9pt;font-family:宋体;">公斤工业结晶醋酸钠，加水至</span><span style="font-size:9pt;">3000</span><span style="font-size:9pt;font-family:宋体;">升，于</span><span style="font-size:9pt;">65<sup>0</sup>C.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">加热钴化</span><span style="font-size:9pt;">5</span><span style="font-size:9pt;font-family:宋体;">小时。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">钴化完毕，加水稀释至</span><span style="font-size:9pt;">12000</span><span style="font-size:9pt;font-family:宋体;">升，于</span><span style="font-size:9pt;">40<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">，必要时可加热到</span><span style="font-size:9pt;">40<sup>0</sup>C. </span><span style="font-size:9pt;font-family:宋体;">压滤（母液为无色）</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">压滤需一台</span><span style="font-size:9pt;">31</span><span style="font-size:9pt;font-family:宋体;">框压滤机，</span><span style="font-size:9pt;"> 120 x 120 x 3.5 cm.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">压滤时间：</span><span style="font-size:9pt;">8</span><span style="font-size:9pt;font-family:宋体;">小时。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">滤饼量：约</span><span style="font-size:9pt;">950</span><span style="font-size:9pt;font-family:宋体;">公斤。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">3. </span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">烘干：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">染料滤饼以薄层状铺于非金属盘（</span><span style="font-size:9pt;">Haveg</span><span style="font-size:9pt;font-family:宋体;">）中，于</span><span style="font-size:9pt;">75<sup>0</sup>C.</span><span style="font-size:9pt;font-family:宋体;">热空气烘箱中烘干。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9pt;font-family:宋体;">得量</span></u></strong><strong><u><span style="font-size:9pt;">:</span></u></strong><span style="font-size:9pt;"><span>  </span>0.6</span><span style="font-size:9pt;font-family:宋体;">公斤分子</span><span style="font-size:9pt;"> = 92</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">5-</span><span style="font-size:9pt;font-family:宋体;">硝基</span><span style="font-size:9pt;">-2-</span><span style="font-size:9pt;font-family:宋体;">氨基苯酚投量</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;"><span>                  </span></span><span style="font-size:9pt;font-family:宋体;">得</span><span style="font-size:9pt;">200</span><span style="font-size:9pt;font-family:宋体;">公斤柴邦坚牢紫</span><span style="font-size:9pt;">BE. </span><span style="font-size:9pt;font-family:宋体;">得率：</span><span style="font-size:9pt;">217%</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;"><span>      </span></span><span style="font-size:9pt;font-family:宋体;">纯染料含量</span><span style="font-size:9pt;">95%<span>  </span></span><span style="font-size:9pt;font-family:宋体;">分子量</span><sup><span style="font-size:9pt;">710</span></sup><span style="font-size:9pt;">/<sub>2</sub> = 190</span><span style="font-size:9pt;font-family:宋体;">公斤纯染料。</span><span style="font-size:9pt;"> </span><strong><u><span style="font-size:9pt;font-family:宋体;">收率：</span></u></strong><span style="font-size:9pt;"> 89%</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产控制：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><strong><u><span style="font-size:9pt;font-family:宋体;">取样</span></u></strong><strong><u><span style="font-size:9pt;">1.</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">用碱性间苯二酚测偶合液。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>            </span></span><strong><u><span style="font-size:9pt;font-family:宋体;">取样</span></u></strong><strong><u><span style="font-size:9pt;">2.</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">为确证反重氮体，酸化并加热到</span><span style="font-size:9pt;">40<sup>0</sup>C. </span><span style="font-size:9pt;font-family:宋体;">有重氮体，用间苯二酚可测出偶合情况。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">原料，含量，杂质和分析方法：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>    </span>5-</span><span style="font-size:9pt;font-family:宋体;">硝基</span><span style="font-size:9pt;">-2-</span><span style="font-size:9pt;font-family:宋体;">氨基苯酚，含量：</span><span style="font-size:9pt;">90%<span>    </span></span><span style="font-size:9pt;font-family:宋体;">分析方法：</span><span style="font-size:9pt;">I.G. Nr. 250 (</span><span style="font-size:9pt;font-family:宋体;">译注：见</span><span style="font-size:9pt;">PB 70189, 6631-2)</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">成品，含量，杂质和分析方法：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">成品与标准品染色比较。纯染料含量：</span><span style="font-size:9pt;">95%</span><span style="font-size:9pt;font-family:宋体;">。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">专利号：</span></u></strong><span style="font-size:9pt;"><span>  </span>DE 535472.<span>     </span></span><strong><u><span style="font-size:9pt;font-family:宋体;">报告号：</span></u></strong><span style="font-size:9pt;"><span>  </span>--<span>         </span></span><strong><u><span style="font-size:9pt;font-family:宋体;">标准号：</span></u></strong><span style="font-size:9pt;"><span>  </span>943.</span> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9pt;"><span>    </span>2003</span></strong><strong><span style="font-size:9pt;font-family:宋体;">年</span></strong><span style="font-size:9pt;">2</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">14</span><span style="font-size:9pt;font-family:宋体;">日。</span><span style="font-size:9pt;"><span>      </span></span><strong><span style="font-size:9pt;font-family:宋体;">译自</span></strong><strong><span style="font-size:9pt;"> PB 73561, 696-700.</span></strong> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">加注：</span></u></strong><strong><span style="font-size:9pt;"><span>  </span></span></strong><span style="font-size:9pt;font-family:宋体;">上面的工艺是第一种方法（</span><span style="font-size:9pt;">I</span><span style="font-size:9pt;font-family:宋体;">），第二种方法，可参见</span><span style="font-size:9pt;">C.I.</span><span style="font-size:9pt;font-family:宋体;">溶剂黑</span><span style="font-size:9pt;">34.</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">本品</span><span style="font-size:9pt;">CAS/EC</span><span style="font-size:9pt;font-family:宋体;">号：</span><span style="font-size:9pt;">1. [6421-643]/ 229-171-1.<span>  </span>= C.I. Solvent Violet 1.</span> <br /> <p class="MsoNormal" style="text-indent:80.2pt;"> <span style="font-size:9pt;"><span> </span>2. [15525-22-1]/ 605-003-6. </span><span style="font-size:9pt;font-family:宋体;">这是色号。</span><span style="font-size:9pt;">- C<sub>16</sub>H<sub>11</sub>N<sub>3</sub>O<sub>4</sub>.<sup>1</sup>/<sub>2</sub> Co.</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;"><span>               </span>3. [32517-38-7]/ 251-080-0.<span>  </span>– C<sub>32</sub>H<sub>18</sub>CoN<sub>6</sub>O<sub>8</sub>. H.</span>   <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000045" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000045</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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