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发 送 文 章     C.I. 酸性黄65 (C.I. 14170) 生产工艺 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <strong><span><span>               </span><u>C.I. </u></span></strong><strong><u><span style="font-family:宋体;">酸性黄</span><span>65 (C.I. 14170) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span> </u><span><span>             </span>CAS</span></strong><strong><span style="font-family:宋体;">号</span><span>: [6408-90-8]</span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">CAS</span></u></strong><strong><u><span style="font-size:9.0pt;font-family:宋体;">名</span></u></strong><strong><u><span style="font-size:9.0pt;">: </span></u></strong><strong><span style="font-size:9.0pt;"><span> </span>Benzenesulfonic acid, </span></strong><span style="font-size:9.0pt;">2-[[4-[[3-methyl-4-[(phenylsulfonyl)oxy]phenyl]amino]-5-nitro-, monosodium salt</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">生产工艺文献：</span></u></strong><strong><span style="font-size:9.0pt;"><span>  </span>BIOS 961,</span></strong><span style="font-size:9.0pt;"> 26.<span>   </span><strong>FIAT 764 – Echtseidegelb G.</strong><span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">未说明</span><span style="font-size:9.0pt;">PB</span><span style="font-size:9.0pt;font-family:宋体;">号。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>                </span><strong>PB 73561, </strong>132-134. <strong>Echtseidegelb G.<span>         </span></strong></span><span style="font-size:9.0pt;font-family:宋体;">译文如下。</span><span style="font-size:9.0pt;">(</span><span style="font-size:9.0pt;font-family:宋体;">一般资料，无。</span><span style="font-size:9.0pt;">)</span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>              </span></span><strong><u><span style="font-size:9.0pt;font-family:宋体;">坚牢丝用黄</span></u></strong><strong><u><span style="font-size:9.0pt;">G </span></u></strong><strong><u><span style="font-size:9.0pt;font-family:宋体;">生产工艺规程</span></u></strong><strong><u><span style="font-size:9.0pt;"> </span></u></strong><strong><span style="font-size:9.0pt;"><span>               </span>Ludwigshafen </span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">厂</span></strong><strong><span style="font-size:9.0pt;"><span>   </span>1943</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">年</span></strong><strong><span style="font-size:9.0pt;">2</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">月</span></strong><strong><span style="font-size:9.0pt;">4</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">日。</span></strong><strong><span style="font-size:9.0pt;"></span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">反应式：</span></u></strong><strong><u><span style="font-size:9.0pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><img src="data:image/png;base64,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" alt="" /></span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;">4-</span><span style="font-size:9.0pt;font-family:宋体;">氨基</span><span style="font-size:9.0pt;">-4-</span><span style="font-size:9.0pt;font-family:宋体;">硝基二苯胺</span><span style="font-size:9.0pt;">-2’-</span><span style="font-size:9.0pt;font-family:宋体;">磺酸钠盐</span><span style="font-size:9.0pt;"> <span> </span><span>M=331.28. <span> </span>CAS</span></span><span style="font-size:9.0pt;font-family:宋体;">号</span><span style="font-size:9.0pt;">: [14846-08-3]</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">投料量：</span></u></strong><span style="font-size:9.0pt;"><span>  </span><sup>5/</sup><sub>10</sub> </span><span style="font-size:9.0pt;font-family:宋体;">分子</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">设备：</span></u></strong><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">略！</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">操作步骤：</span></u></strong><strong><u><span style="font-size:9.0pt;"></span></u></strong> <br /> <p class="MsoNormal"> <u><span style="font-size:9.0pt;">1.<span>  </span></span></u><u><span style="font-size:9.0pt;font-family:宋体;">重氮化：</span></u><u><span style="font-size:9.0pt;"></span></u> <br /> <p class="MsoNormal" style="text-indent:18.0pt;"> <span style="font-size:9.0pt;font-family:宋体;">在</span><span style="font-size:9.0pt;">4000</span><span style="font-size:9.0pt;font-family:宋体;">升溶解锅内，加入</span><span style="font-size:9.0pt;">2000</span><span style="font-size:9.0pt;font-family:宋体;">升水，</span><span style="font-size:9.0pt;">156</span><span style="font-size:9.0pt;font-family:宋体;">公斤，</span><span style="font-size:9.0pt;">100% </span><span style="font-size:9.0pt;font-family:宋体;">氨基硝基二苯胺磺酸钠盐和</span><span style="font-size:9.0pt;">6</span><span style="font-size:9.0pt;font-family:宋体;">公斤碳酸钠，搅拌煮沸溶解，然后加入</span><span style="font-size:9.0pt;">8</span><span style="font-size:9.0pt;font-family:宋体;">公斤活性炭，再煮沸</span><span style="font-size:9.0pt;">10</span><span style="font-size:9.0pt;font-family:宋体;">分钟，最后通过滤清压滤机过滤，滤液回到溶解锅内，搅拌过夜，加入</span><span style="font-size:9.0pt;">35</span><span style="font-size:9.0pt;font-family:宋体;">公斤，</span><span style="font-size:9.0pt;">100% </span><span style="font-size:9.0pt;font-family:宋体;">亚硝酸钠，物料冷到</span><span style="font-size:9.0pt;">25<sup>0</sup>C.</span><span style="font-size:9.0pt;font-family:宋体;">，在</span><span style="font-size:9.0pt;">2</span><span style="font-size:9.0pt;font-family:宋体;">小时内慢慢放料到</span><span style="font-size:9.0pt;">10000</span><span style="font-size:9.0pt;font-family:宋体;">升重氮锅内，重氮锅预先加好</span><span style="font-size:9.0pt;">1200</span><span style="font-size:9.0pt;font-family:宋体;">公斤冰和</span><span style="font-size:9.0pt;">400</span><span style="font-size:9.0pt;font-family:宋体;">升</span><span style="font-size:9.0pt;">11<sup>0</sup></span><span style="font-size:9.0pt;font-family:宋体;">波美盐酸，温度控制在</span><span style="font-size:9.0pt;">0-3<sup>0</sup>C.</span><span style="font-size:9.0pt;font-family:宋体;">，加毕，再搅拌</span><span style="font-size:9.0pt;">3</span><span style="font-size:9.0pt;font-family:宋体;">小时。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18.0pt;"> <strong><span style="font-size:9.0pt;font-family:宋体;">取样：</span></strong><span style="font-size:9.0pt;font-family:宋体;">重氮化开始到反应完，亚钠反应是从强到弱。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <u><span style="font-size:9.0pt;">2.<span>  </span></span></u><u><span style="font-size:9.0pt;font-family:宋体;">偶合：</span></u><u><span style="font-size:9.0pt;"></span></u> <br /> <p class="MsoNormal" style="text-indent:18.0pt;"> <span style="font-size:9.0pt;font-family:宋体;">在</span><span style="font-size:9.0pt;">6000</span><span style="font-size:9.0pt;font-family:宋体;">升溶解锅内先加入</span><span style="font-size:9.0pt;">700</span><span style="font-size:9.0pt;font-family:宋体;">升</span><span style="font-size:9.0pt;">40-50<sup>0</sup>C.</span><span style="font-size:9.0pt;font-family:宋体;">热水和</span><span style="font-size:9.0pt;">42</span><span style="font-size:9.0pt;font-family:宋体;">公斤，</span><span style="font-size:9.0pt;">50%</span><span style="font-size:9.0pt;font-family:宋体;">液碱，再加入</span><span style="font-size:9.0pt;">60</span><span style="font-size:9.0pt;font-family:宋体;">公斤邻甲基苯酚溶解，溶解后加到预先加有</span><span style="font-size:9.0pt;">2500</span><span style="font-size:9.0pt;font-family:宋体;">升水和</span><span style="font-size:9.0pt;">800</span><span style="font-size:9.0pt;font-family:宋体;">公斤冰的</span><span style="font-size:9.0pt;">45000</span><span style="font-size:9.0pt;font-family:宋体;">升偶合锅内，控制偶合温度为</span><span style="font-size:9.0pt;">5<sup>0</sup>C.</span><span style="font-size:9.0pt;font-family:宋体;">，在</span><span style="font-size:9.0pt;">1.5</span><span style="font-size:9.0pt;font-family:宋体;">小时内加入上述重氮液（重氮液如有析出，需略加稀释），加毕，搅拌过夜。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18.0pt;"> <strong><span style="font-size:9.0pt;font-family:宋体;">取样：</span></strong><span style="font-size:9.0pt;font-family:宋体;">偶合完毕，邻甲基苯酚应微过量。偶合完毕，加入</span><span style="font-size:9.0pt;">300</span><span style="font-size:9.0pt;font-family:宋体;">升</span><span style="font-size:9.0pt;">11<sup>0</sup></span><span style="font-size:9.0pt;font-family:宋体;">波美盐酸酸化到刚果红呈弱酸性，然后加入</span><span style="font-size:9.0pt;">200</span><span style="font-size:9.0pt;font-family:宋体;">公斤食盐，搅拌</span><span style="font-size:9.0pt;">3</span><span style="font-size:9.0pt;font-family:宋体;">小时使染料析出，用压滤机</span><span style="font-size:9.0pt;">(145 x 145 x 3.5 cm – 23</span><span style="font-size:9.0pt;font-family:宋体;">框</span><span style="font-size:9.0pt;">)</span><span style="font-size:9.0pt;font-family:宋体;">压滤。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <u><span style="font-size:9.0pt;">3.<span>  </span></span></u><u><span style="font-size:9.0pt;font-family:宋体;">酯化：</span></u><u><span style="font-size:9.0pt;"></span></u> <br /> <p class="MsoNormal" style="text-indent:18.0pt;"> <span style="font-size:9.0pt;font-family:宋体;">将滤饼用</span><span style="font-size:9.0pt;">5000</span><span style="font-size:9.0pt;font-family:宋体;">升热水和</span><span style="font-size:9.0pt;">30</span><span style="font-size:9.0pt;font-family:宋体;">公斤碳酸钠搅拌过夜溶解，然后加入</span><span style="font-size:9.0pt;">40</span><span style="font-size:9.0pt;font-family:宋体;">公斤</span><span style="font-size:9.0pt;">40<sup>0</sup></span><span style="font-size:9.0pt;font-family:宋体;">波美液碱和</span><span style="font-size:9.0pt;">165</span><span style="font-size:9.0pt;font-family:宋体;">公斤碳酸钠。<strong>取样：</strong>测</span><span style="font-size:9.0pt;">pH = 11. </span><span style="font-size:9.0pt;font-family:宋体;">调整完毕，在</span><span style="font-size:9.0pt;">25<sup>0</sup>C.</span><span style="font-size:9.0pt;font-family:宋体;">，半小时内分小份加入</span><span style="font-size:9.0pt;">85</span><span style="font-size:9.0pt;font-family:宋体;">公斤苯磺酰氯，加毕搅拌过夜。<strong>取样</strong></span><strong><span style="font-size:9.0pt;">;</span></strong> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;font-family:宋体;">在</span><span style="font-size:9.0pt;">24</span><span style="font-size:9.0pt;font-family:宋体;">小时内，应随时测溶液的碱性。</span><span style="font-size:9.0pt;">pH = 9-10, </span><span style="font-size:9.0pt;font-family:宋体;">样品用水稀释，其渗圈用稀碱滴，应无沉淀出现（与标准品比较），合格后加入</span><span style="font-size:9.0pt;">500</span><span style="font-size:9.0pt;font-family:宋体;">公斤氯化钾盐析。<strong>取样</strong></span><strong><span style="font-size:9.0pt;">;</span></strong><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">过滤母液再加氯化钾应不再有染料析出。用压滤机过滤。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <u><span style="font-size:9.0pt;font-family:宋体;">烘干：</span></u><span style="font-size:9.0pt;"><span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">滤饼用衬铅铁盘于</span><span style="font-size:9.0pt;">45-50<sup>0</sup>C.</span><span style="font-size:9.0pt;font-family:宋体;">烘箱中烘干。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <u><span style="font-size:9.0pt;font-family:宋体;">磨粉：</span></u><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">物料用</span><span style="font-size:9.0pt;">3000</span><span style="font-size:9.0pt;font-family:宋体;">转</span><span style="font-size:9.0pt;">Simag</span><span style="font-size:9.0pt;font-family:宋体;">磨粉，过</span><span style="font-size:9.0pt;">1mm</span><span style="font-size:9.0pt;font-family:宋体;">筛，加芒硝标准化。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">得量：</span></u></strong><span style="font-size:9.0pt;"><span>  </span><strong>262</strong></span><strong><span style="font-size:9.0pt;font-family:宋体;">公斤。强度</span></strong><span style="font-size:9.0pt;"> 72/100 = 365</span><span style="font-size:9.0pt;font-family:宋体;">公斤标准强度，得量</span><span style="font-size:9.0pt;"> = 230%</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9.0pt;"> </span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">加注：</span></u></strong><strong><u><span style="font-size:9.0pt;"></span></u></strong> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9.0pt;font-family:宋体;">用对甲苯磺酰氯酯化，得</span><strong><span style="font-size:9.0pt;">C.I. </span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">酸性黄</span></strong><strong><span style="font-size:9.0pt;">65:1. </span></strong><span style="font-size:9.0pt;font-family:宋体;">钠盐</span><span style="font-size:9.0pt;"> CAS</span><span style="font-size:9.0pt;font-family:宋体;">号</span><span style="font-size:9.0pt;">;[83006-49-9]</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9.0pt;"><span>                                      </span></span><span style="font-size:9.0pt;font-family:宋体;">钾盐</span><span style="font-size:9.0pt;"> CAS</span><span style="font-size:9.0pt;font-family:宋体;">号</span><span style="font-size:9.0pt;">:[68959-04-6]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9.0pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9.0pt;"><span>    </span>2016</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">年</span></strong><strong><span style="font-size:9.0pt;">3</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">月</span></strong><strong><span style="font-size:9.0pt;">2</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">日。</span></strong><strong><span style="font-size:9.0pt;"></span></strong> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000064" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000064</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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