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发 送 文 章     C.I. 分散黄61 (C.I. 48005) 生产工艺 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <span><strong><u>C.I. </u></strong></span><strong><u><span style="font-family:宋体;">分散黄</span><span>61 (C.I. 48005) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span> </u><span><span>  </span>CAS</span></strong><strong><span style="font-family:宋体;">号</span><span>:[4421-21-0]</span></strong> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">名：</span></u></strong><strong><span style="font-size:9pt;"> 2-Propenoic acid,</span></strong><span style="font-size:9pt;"> 2-cyano-3-[4-[(4-ethoxyphenyl)methylamino]phenyl]-, ester.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">发明者：</span></u></strong><span style="font-size:9pt;"><span>  </span>I.G.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产工艺文献：</span></u></strong><strong><span style="font-size:9pt;"><span>  </span>FIAT 1313,III</span></strong><span style="font-size:9pt;">, 126-127.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">无工艺。</span><span style="font-size:9pt;"><span>  </span><strong>FIAT 764 – Cellitonechtgelb 3G “F”.</strong><span>  </span></span><span style="font-size:9pt;font-family:宋体;">无具体资料名。</span><span style="font-size:9pt;"></span> <strong><span style="font-size:9pt;">PB 74026, </span></strong><span style="font-size:9pt;">2405. <strong>Cellitonechtgelb 3G.<span>  </span></strong></span><span style="font-size:9pt;font-family:宋体;">这是按调査团要求填写的简要生产工艺。抄录如下：</span><span style="font-size:9pt;"></span> <br /> <span style="font-size:9pt;"><strong><u>Cellitonechtgelb 3G </u></strong></span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">反应式：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">（本人有加注）</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><img alt="" src="data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAfcAAABVCAIAAADbtDohAAAKn0lEQVR4nO2ay7LcIAxE5/9/2lkkNfGgBy3AIHCfRcqDhZBBarBvPhchhJBz+awOgBBCyINQ5Qkh5GSo8oQQcjJUeUIIORmqPCGEnAxVnhBCToYqTwghJ0OVJ4SQk6HKkwF8bnx/FreWBkjIe2HtkV7uCn4Xd9WAEDIZlh/pwlLw4jg/MSJCZlO8y17JXmdZfqQLR+WLfwk5Euu1Nc/rLMuPdEGVJ2/Gye08r7N7lN+ng11CnRznKHyVv35znUxml8LZIkgrcv/WJ8FBZ/00VemZoPnJuqTvWj7am6naSGbSOe3TVm3rqqHKj2GXZO0ca3m+9lCcreTPdaG9l10KZ+uqqar8leB1Nnv59c/OFsk6ygMhfxmSSxMS8oCqsV5b87zOppaV6tSAm+ScKd6lrsgb8BMJ/K79dDYeUzJyPlO9zq6fIAd1auTfXpC/xizM14+gzU9adoz5bKwVqYoR7moIb66ameSdHUviq73aOvbgFxXe7ntLy3YBH49cEUQonTQeFhng9iVVM5O8U6NmanPfUPcoDUXl2GyXr9sFfDa7FM4xVZM//5PG15OpozzMGShbykbZKNQ38EThNDhpGGXfqslfAhnjGyXQc4S+8NkwxLQN6Qk2CvUN9Gej2mvsKg/xn6Rqtsj/jCEOyVSrY8J8HehnPrvE+QYGZtGjCfmQyoN+PjeKluIa95Cc+t/inedBnjY6HWPTK3+yOh3T5lB/nRwPPiHVIsLns7AZWzidDh0nA6um6upugFzjHjID/c26uuROglZtnC6hjqA3x6ElW7jzyRtSSG1HiW9/nexLaA6HFEib+iD2PmDhNCTYwq0IvNXmITONj91wskB6jc1Uq3v/Yqt3k4SqXkclGFElMJ7D+PziW6rXfqNvEFqXOQkZWve1VeNnb7Gs6kJvmtiBxy7u1l0He03LVL8dXNHM+VpcD9lukXFB+Xuaz3SQMFSD6oOAXdr8R0e3QvpgJWN1bw3Q7B6aJXkLNNuI2GN/V9SfCMum8IlUS/+0VotQGiPPiA/UH2doLDmlodLyVyRaJ44Ibko1Y++W8hrRxIYK8kdvoxre3axaMtbdOVVTXS/1ieQMb5rM4aKVd2WvBnGx7k5IArmKavzV8n4oVDl0Q75GQwWLBxl308JQqU5+YSyv1UbZK7pw82sHKZmrthU9GqQ6dPTaH3GX3A6/wiD5iue0MyjeK+QQbMeVtOoTZFQBP6ryqn/8+lX0TFS0goYnJJ6NYMlYPicX+KVt1fcWZCMPbfYZqOyEl3gka3bujZarejRTkrVBwhAnT+TrKLUdK7t4nWxUCWMBK0jeRQysEastofgbRpkcpNX9tVlnEZ6OhoXs9D9N5f1q7PGM0OAQV1vVeAKsN8lDFbSkcEIlY3lojdHszqwrCEwHeKDolJKBy/Z0BgxM2SOTdcm+kpmnK2hUQj6ajYdVzRbpnTHEIXkwIQM22pCeY4sgX8KoLNpX5ZdkY/4SSBpf//r1ZypivMuG9By7xPkSFhYOPtBhVZO/BJLG17OE1gvvkHRHzPr3kvx582WjUF+C9fW8ra/fHrVxLLeums8Ntd2yx13JjvjHvbwl6jxktFf1Vo99W5z+EHtJ517RHk9bUjkZ2ynfuOWEregJ7uP2XPu3QjZlF8RoCb5eq3vaQIkPdWlIuyFFlYE5p5i2I8xrcVLr0cLpN64Gk61q8Hi+c25ZopJ9kspf494T2zKgX+Wv30JCiio07nKshIte+7dAA/JlYFFMVvnvrV2qZonKg3PyvwtitJAhi/e0yjcP8ZyfCUzOb6p8iCWF87T9034GDj2wCgo1V699xc9eLf3r1+xhScpupF/zVT56hHkzW2TjFkG2jT6qCmQvS+W9IJ17SehcxWlJsHBDWgLP8smZWThyA77/dPbmA6qmKsHg9VhXP2698HPQs4rN32qsHPXPkvNDXcgElS9UQx2CR3uHOQnZq0H7V40lC9F29ZbMdlWL9lb5S7yth2gYS16/J19DRMvbmUZ56/4v7ofcmVA4YDmwapoBn9Gb4XHBnIA1U7isPF1U2bDij7Zbtz7A69S+s3cAvnyDGf62qsHBZ88zGB3V3liT9bbcSgI41VyRhfgqX1yzfJbAGf/BUXl5zZR9Gqp8fkIqX+1CnoDT/UNI5f0upJMh76pkAoia389G0wIjf+GMl1RTk6cSQgrklnxvKe6yaibD6VaQSWnl68WUJSQIS2YynO5emLKEgPAL2xI44+0wZScjJ9xqUdcF6U7IeTDFyX8+N5y7ly2m1pcuq6UhQqel+iXN707IkTDFyT+QPzb02Az5YwYu01R5Qv7CFCfX1fQ/0x15lf+bYpS8In6c1wWqPHkhTHEU9WsD/lHCsnw0Zhxc5f2vOl9X939V//6I1kA8yx9AtWqqX/bS1lFOZs9OVSOk5QWs+vW72Lj44mHL6zbF8TVrFX5FqY9cLE1hg6t8aF2o8rujppBvID04XYhk6uxEBW6U/VhhdeQJ3L0GBjMK/NxkdZGCbm0P9xa1zr991d0ajPwklVenwrcsrn172df3PIp7nEWjvC66yEZiMW92GlaiQeVVremPxOke0p3M2RlS8IHX8qcToVQEVafUsardc9JQBcPtoz6RQaM5dm/JXEcJya7yat36QxR5EFV5f1C1b2iI4QUzEP+p73elvKoeZDU65U0kbVUT6u6sl9U4asnUTHDid/JqSDynsl7lo7t6kZSF9FwiV/wcBfeP6iOAlnJ0cOi1VOPseZBdJmEJbSrvHFOsIaTCOjH4bvEAGlRe9cwU8lmv8pe9rsj1vcXaCazh1MyuZhKS9MeoPKIUnRIf2mjfhp9I3wQGq8YpEFVhLelX/TQQVXm/I7GYOjs9au7v8M191RY18kL65U7g7A3WLQoc8fFlDs98KeWyLyL9alTyp5rw8q78WdggI7KOqsyeGnVJ5JoVllJPZfeqjZVzQ56LkIdAxK6q8s6tHv/yJ0lIihVSVR60lz+bhyYkJ8jZSFo65x7V3rJxYlAtSTbWL0/0hcs/sz86NCF5cBR5uP0oS7IELg8h++Gc2YfbV83i4ZOpcIUIIeRkqPKEEHIye6i8fH8sPs2rd6WB9bcjv7vThV/2C+SXAeuu1eLbq27VLlwXouZbYeAbI5mG2FuKFHygRvYoA2cq5TVoDHb3g3HM3olfRcW1P2/qPFerzvdAXoV/PihkV+3lqDZuH3U+nD3KAN+NnY5VA1zlqSYWUZUfqNrcfUmBU93OOSMqxFT5Mci1kXuyv29fkQVA3qeWrFZ+QiqvdrEc+huDlRih4MlhUOX/DTRnmE4K/ZWNV8eCfW5UHVpRYc9xPg0qL3+qPtWlv9tYiUFeS1Urqu9/uAg49lR5CHVVpBb7a+Yf1f0h1CMk1UTSo/L+PPvrYi1018OQzZElryLt1ZaQfTU51e4PsUcZ9Ku8P6HqSRDphZi9ih6V9322bedg2ORI/Dy5gLRxUgi3p8pDVHfUQqaRXfdurDZaC4Y7fyH4SqkzKS19h2oXNRjyQnCV//xSNKqe2+z98B5ijzJIXq7Jw5tJqqlIFQyZT/IEoMr/4B/iFpI2sFUkmZAkYZC1pE2DyYGle35CCCEDocoTQsjJUOUJIeRkqPKEEHIyfwDG7QK+Xp2iDwAAAABJRU5ErkJggg==" /></span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;">4-[N-</span><span style="font-size:9pt;font-family:宋体;">甲基</span><span style="font-size:9pt;">-N-(4-</span><span style="font-size:9pt;font-family:宋体;">乙氧基苯基</span><span style="font-size:9pt;">)</span><span style="font-size:9pt;font-family:宋体;">氨基</span><span style="font-size:9pt;">]</span><span style="font-size:9pt;font-family:宋体;">苯甲醛</span><span style="font-size:9pt;"><span>  </span>+<span>  </span>2-</span><span style="font-size:9pt;font-family:宋体;">氰基乙酸乙酯</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:Wingdings;"><span><span style="font-size:9pt;font-family:宋体;">→</span></span></span><span style="font-size:9pt;"><span>  </span>C.I. </span><span style="font-size:9pt;font-family:宋体;">分散黄</span><span style="font-size:9pt;">61.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">加注：</span></u></strong><span style="font-size:9pt;"> <br />   </span><span style="font-size:9pt;font-family:宋体;">鉴于本品目前已不再使用，所以无工厂生产，目前只能作为历史性产品供参考。另外，我也未做深入调査，它应该有原始生产工艺，至少有品种卡片，</span><span style="font-size:9pt;">Celliton </span><span style="font-size:9pt;font-family:宋体;">商品名，见</span><span style="font-size:9pt;">PB 74706.</span><span style="font-size:9pt;font-family:宋体;">。调査团调査报告，内容有</span><span style="font-size:9pt;">15</span><span style="font-size:9pt;font-family:宋体;">项，其中第</span><span style="font-size:9pt;">9</span><span style="font-size:9pt;font-family:宋体;">项是生产工艺，第</span><span style="font-size:9pt;">10</span><span style="font-size:9pt;font-family:宋体;">项是产品生产控制等，也有</span><span style="font-size:9pt;">PB</span><span style="font-size:9pt;font-family:宋体;">号。</span><span style="font-size:9pt;"></span> <br />   <span style="font-size:9pt;font-family:宋体;">现在，提出创新，新与旧是两个对立的东西，不知道旧，哪知道新，而这些旧资料，在参考书里，在网上是查不到的，所以有人利用它出版所谓新技术图书，有人所发表的一些中国专利，其实也不是新的，因为专利審査人不是专家，有的也是从公开资料或上网査一下。所谓知识产权，一般体现在专利中，不会公开公布其生产工艺，</span><span style="font-size:9pt;">PB</span><span style="font-size:9pt;font-family:宋体;">报告是特例。美国人和日本人利用它进一步开发了新产品，也收到了美元，而我们把它放在书库内，可惜！可惜！我只是利用了很小的一部分，我免费提供的“化学文库”也只是一部分，请读者慢慢看吧！我是尽量利用余生把它提供给大家，谢谢！</span><span style="font-size:9pt;"></span> <br />   <span style="font-size:9pt;font-family:宋体;">现将</span><span style="font-size:9pt;">Cellitonechtgelb 3G</span><span style="font-size:9pt;font-family:宋体;">原文抄录如下。</span><span style="font-size:9pt;"></span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Apparatur:</span></u></strong> <br />   <span style="font-size:9pt;">2000 l gusseiserne Ruehrwerkapfanne.</span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Verfahren:</span></u></strong> <br />   <span style="font-size:9pt;">150 kg. Aethoxyphenylaldehyd</span> <br />   <span style="font-size:9pt;">68 kg. Cyanoessigsaureaethylester</span> <br />   <span style="font-size:9pt;">18 kg. Methanol</span> <br />   <span style="font-size:9pt;">1 kg. Piperidin warden unter Ruehren auf 95-100<sup>0</sup> erhitzt, nach dem Festwerden der Schmelze noch 3 Stdn. Auf Temperatur gehalten. Der Pfanneninhalt ist dann zu einen frei an Pulver verruehrt.</span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Ausbeute:</span></u></strong> <br />   <span style="font-size:9pt;">195-200 kg. Cellitonechtgelb 3G</span><span style="font-size:9pt;font-family:宋体;">“</span><span style="font-size:9pt;">F”</span> <p class="MsoNormal"> <span style="font-size:9pt;">Fp. 84-86<sup>0</sup></span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">FIAT 1313,III, 12-127.</span></u></strong><span style="font-size:9pt;"></span> <br />   <span style="font-size:9pt;">Celliton Yellow 3G was </span><span style="font-size:9pt;font-family:宋体;">结构式，见上。</span><span style="font-size:9pt;"></span> <br />   <span style="font-size:9pt;">A new silk yellow with low tinctorial strength but excellent light fastness was</span> <br />   <span style="font-size:9pt;">45% 2-nitro-4-cyano diphenylamine</span> <br /> <span style="font-size:9pt;">  45% Dispersing Agent SS</span> <br />   <span style="font-size:9pt;">7% Very pure CaSO<sub>4</sub></span> <br />   <span style="font-size:9pt;">3% Nekal BX</span>   <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000077" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000077</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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