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发 送 文 章     C.I. 溶剂红109 (C.I. 13900/45170) 生产工艺 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <span><strong><u>C.I. </u></strong></span><strong><u><span style="font-family:宋体;">溶剂红</span><span>109 (C.I. 13900/45170) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span> </u></strong> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">名：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;">CAS</span><span style="font-size:9pt;font-family:宋体;">号</span><span style="font-size:9pt;"> [3375-25-5] </span><span style="font-size:9pt;font-family:宋体;">和</span><span style="font-size:9pt;">[85443-53-4]</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">发明者：</span></u></strong><span style="font-size:9pt;"><span>  </span>F. Straub, G. Montmollin, J. Spieler, C. v. Planta<span>  </span>1924</span><span style="font-size:9pt;font-family:宋体;">年。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产工艺文献：</span></u></strong><strong><span style="font-size:9pt;"><span>  </span>FAT 1313,III, 133 – Component of Zapon Fast Fire Red B Extra</span></strong> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">Zapon Fast Fire Red B </span></strong><span style="font-size:9pt;">was a mixture of <strong>Rhodamine 4GD </strong>Extra plus <strong>Palatine Fast Yellow GRN. </strong></span><strong><span style="font-size:9pt;font-family:宋体;">？？？</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">PB 73561, </span></strong><span style="font-size:9pt;">647-648. <span> </span><strong>Rhodamine B </strong>extra plus <strong>Palatinechtgelb GRNX.</strong></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <u><span style="font-size:9pt;font-family:宋体;">参考文献：</span></u><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">世界染料品种</span><span style="font-size:9pt;"> <span>– 2005</span></span><span style="font-size:9pt;font-family:宋体;">年。</span><span style="font-size:9pt;">P. 951.</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9pt;">Fabrikationsvorschrift fuer Zaponechtfeur WL-720 </span></u></strong><span style="font-size:9pt;"><span>    </span><span> </span>1932</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">8</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">23</span><span style="font-size:9pt;font-family:宋体;">日</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">抄自</span><span style="font-size:9pt;"> PB 73561, 647.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">结构式：</span></u></strong><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">本人有加注。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><img alt="" src="data:image/png;base64,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" /></span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>   </span>Rhodamine B = C.I. </span><span style="font-size:9pt;font-family:宋体;">碱性紫</span><span style="font-size:9pt;">10 </span><span style="font-size:9pt;font-family:宋体;">（碱式）</span><span style="font-size:9pt;">+<span>  </span>Palatinechtgelb GRNX = C.I. </span><span style="font-size:9pt;font-family:宋体;">酸性黄</span><span style="font-size:9pt;">99 </span><span style="font-size:9pt;font-family:宋体;">（酸式）</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Einsatz: </span></u></strong><strong><span style="font-size:9pt;"><span>  </span><sup>1</sup>/<sub>10</sub> Kilo Mol.</span></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">85 kg <strong>Palatinechtgelb GRNX </strong>werden in <strong>5000 l. Wasser</strong> von <strong>50<sup>0</sup></strong> geloest. Zeigt die Loesung schwach alkalische Reaktion, so wird sie durch Zugabe von ca. <strong>14 kg Eisessig </strong>technisch schwach lackmussauer gestellt. In diese Loesung fliesst unter gutem Ruehren ein eine Loesung von <strong>49 kg Rhodamin B </strong>extra in <strong>2000 l. Wassr</strong> von <strong>50<sup>0</sup></strong>. Dauer des Einlaufens ca. <strong>2 Stunden. </strong>Sogleich nach Beginn des Einlaufens der <strong>Rhodamin</strong> Loesung wird zweckmaessigeweise mit etwas <strong>Zaponechtfeuerrot WL 720</strong> angeimpft, um von vorherein eine <strong>kristalline</strong> Abscheidung zu gewaehhrleisten. Man ruehrt ueber Nacht. Das Zaponechtfeuerrot WL 720 scheidet sich quantitativ aus. Der Auslauf auf Papier ist praktisch <strong>farblos.</strong> Man presst ab und waescht mit ca. <strong>300 l. Wasser</strong> nach. Man benoetigt eine Presse zu <strong>24 Rahmen.<span>  </span></strong>Rahmengroese 75 x 75 x 3cm.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">Dauer des Fuellens einer Presse ca. 1 Stunde.<span>  </span><strong>Gewicht </strong>des presskuchens ca. <strong>400 kg.<span>  </span></strong>Das Pressgut wird sodann auf Holzhorden oder Haung-Schalen bei <strong>55<sup>0</sup></strong> getrocknet und auf der Kolloplexmuehlen.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">Ausbeute</span></u></strong><span style="font-size:9pt;"> aus <sup>1</sup>/<sub>10</sub> Kilo mol = <strong>85 kg</strong> Palatinechtgelb GRNX =<strong>96 kg Zaponechtfeuerrot WL 720</strong> = 113% Betriebsausbeute.<span>   </span><strong>Reinfarbstoff 99% = 95 kg Reinfarstoff = 100% der Theore.</strong></span> <strong><span style="font-size:9pt;"> </span></strong> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">Zaponechtfeuerrot B extra</span></u></strong><strong><span style="font-size:9pt;"><span>    </span>1939</span></strong><strong><span style="font-size:9pt;font-family:宋体;">年</span></strong><strong><span style="font-size:9pt;">11</span></strong><strong><span style="font-size:9pt;font-family:宋体;">月</span></strong><strong><span style="font-size:9pt;">16</span></strong><strong><span style="font-size:9pt;font-family:宋体;">日</span></strong><span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">抄自</span><span style="font-size:9pt;">PB73561, 648.</span> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">(Ergaenzung zur Betriebsvorschrift)<span>     </span></span><span style="font-size:9pt;font-family:宋体;">这里已改用火红</span><span style="font-size:9pt;">B= Zapon Fast Fire Red B</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><span style="font-size:9pt;">120 kg Palatinechtgelb GRN, 4000 l. </span></strong><span style="font-size:9pt;">Kondenswasser von <strong>60<sup>0</sup></strong>. In dieser Loesung unter guter Ruehren zufliessen lassen eine Loesung von <strong>49 kg Rhodamin B Extra</strong> in <strong>2000 l. </strong>Kondenswasser von <strong>60<sup>0</sup></strong>. Dauer des Einlaufens <strong>2 Stunden.<span>  </span></strong>Animpfen bleibt; ueber Nacht ruehren</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">Sonst wie Originalvorschrift: <strong>Ausbeute 56.3% = 96 kg.</strong></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">加注：</span></u></strong><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">按</span><strong><span style="font-size:9pt;">FIAT 1313,III, 133.</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">它是</span><strong><span style="font-size:9pt;">Rhodamine 4GD</span></strong><span style="font-size:9pt;"> Extra (C.I. </span><span style="font-size:9pt;font-family:宋体;">碱性红</span><span style="font-size:9pt;">1) </span><span style="font-size:9pt;font-family:宋体;">加</span><span style="font-size:9pt;"> <strong><span>Palatine Fast Yellow GRN </span></strong><span>(<strong>C.I. </strong></span></span><span style="font-size:9pt;font-family:宋体;">酸性黄</span><span style="font-size:9pt;">99). </span><span style="font-size:9pt;font-family:宋体;">即</span><strong><span style="font-size:9pt;">(C.I. 13900 / 45160).</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">如果读者感兴趣，请看</span><strong><span style="font-size:9pt;">PB 73561,</span></strong><span style="font-size:9pt;"> 649</span><span style="font-size:9pt;font-family:宋体;">和</span><span style="font-size:9pt;">670.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">Fabrikationsvorschrift fuer Zaponechtfeuerrot 4GD </span></u></strong><u><span style="font-size:9pt;">Extra.</span></u><span style="font-size:9pt;"><span>    </span>1933</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">5</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">17</span><span style="font-size:9pt;font-family:宋体;">日和</span><span style="font-size:9pt;">1939</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">11</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">16</span><span style="font-size:9pt;font-family:宋体;">日。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"> </span> <strong><span style="font-size:9pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9pt;"><span>  </span></span></strong><span style="font-size:9pt;">2016</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">5</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">20</span><span style="font-size:9pt;font-family:宋体;">日</span><span style="font-size:9pt;"><span>     </span></span><span style="font-size:9pt;font-family:宋体;">于</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">无锡</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">明辉国际。</span><span style="font-size:9pt;"></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000133" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000133</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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