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发 送 文 章     C.I. 颜料棕28 = C.I. 还原棕3 (C.I. 69015) 生产工艺 CAS号[131-92-0] [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <span><strong><u>C.I. </u></strong></span><strong><u><span style="font-family:宋体;">颜料棕</span><span>28 = C.I. </span></u></strong><strong><u><span style="font-family:宋体;">还原棕</span><span>3 (C.I. 69015) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span></u><span><span>    </span>CAS</span></strong><strong><span style="font-family:宋体;">号</span><span>[131-92-0]</span></strong> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">名</span></u></strong><strong><u><span style="font-size:9pt;">:</span></u></strong><strong><span style="font-size:9pt;"> Benzamide, </span></strong><span style="font-size:9pt;">N,N’-(10,15,16,17-tetrahydro-5,10,15,17-tetraoxo-5H-dinaphtho[2,3-a:2’,3’-i]carbazole-</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>                    </span>-4,9-diyl)bis-</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">发明者：</span></u></strong><span style="font-size:9pt;"><span>  </span>W. Mieg<span>  </span>1910</span><span style="font-size:9pt;font-family:宋体;">年。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产工艺文献：</span></u></strong><strong><span style="font-size:9pt;"><span>   </span>BIOS 1493,</span></strong><span style="font-size:9pt;"> 12-13.<strong> Indanthrene Brown R<span>      </span></strong></span><span style="font-size:9pt;font-family:宋体;">见抄录文。</span><span style="font-size:9pt;"></span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">FIAT 1313,II, </span></strong><span style="font-size:9pt;">106-107.<strong> Indanthrene Brown R Paste<span>         </span></strong></span><span style="font-size:9pt;font-family:宋体;">见抄录文。</span><span style="font-size:9pt;"></span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">FIAT 764 – Indanthrenbraun R, FFR. <span>  </span><span>  </span></span></strong><span style="font-size:9pt;font-family:宋体;">原版</span><span style="font-size:9pt;"> <strong><span>Colour Index </span></strong></span><span style="font-size:9pt;font-family:宋体;">未说明</span><span style="font-size:9pt;">PB</span><span style="font-size:9pt;font-family:宋体;">报告号。</span><span style="font-size:9pt;"></span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">PB 25628, </span></strong><span style="font-size:9pt;">3397. <strong>Indanthrenbraun FFR.<span>    </span></strong></span><span style="font-size:9pt;font-family:宋体;">德文。</span><span style="font-size:9pt;"><span>   </span>1935</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">11</span><span style="font-size:9pt;font-family:宋体;">月。</span><span style="font-size:9pt;"><span>  </span>1</span><span style="font-size:9pt;font-family:宋体;">美元。</span><span style="font-size:9pt;"><span>     </span></span><span style="font-size:9pt;font-family:宋体;">未抄录。</span><span style="font-size:9pt;"></span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">PB 74778.</span></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">品种卡片。</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">德文。</span><span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">未抄录。</span><span style="font-size:9pt;"></span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">PB 82232,</span></strong><span style="font-size:9pt;"> 956-958.<span>  </span><strong>Indanthrenbraun FFR.<span>   </span></strong></span><span style="font-size:9pt;font-family:宋体;">德文原件。</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">未抄录。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">日文译文</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">细田豊</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">《理论制造染料化学》</span><span style="font-size:9pt;"> 1957</span><span style="font-size:9pt;font-family:宋体;">年。</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">第</span><span style="font-size:9pt;">710</span><span style="font-size:9pt;font-family:宋体;">页。</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">见抄录文</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">中文译文：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">周春隆</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">穆振义</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">《有机颜料品种及应用手册》</span><span style="font-size:9pt;"> 2011</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">6</span><span style="font-size:9pt;font-family:宋体;">月。</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">第</span><span style="font-size:9pt;">560</span><span style="font-size:9pt;font-family:宋体;">页。</span><span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">中国石化出版社。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:0cm;"> <span style="font-size:9pt;font-family:宋体;">同上</span><span style="font-size:9pt;"><span>       </span></span><span style="font-size:9pt;font-family:宋体;">《有机颜料化学及工艺学》</span><span style="font-size:9pt;"><span>  </span>2014</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">6</span><span style="font-size:9pt;font-family:宋体;">月。</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">第</span><span style="font-size:9pt;">748</span><span style="font-size:9pt;font-family:宋体;">页。</span><span style="font-size:9pt;"><span>        </span></span><span style="font-size:9pt;font-family:宋体;">同上</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">项</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">斌</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">高建荣</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">化工产品手册，第五版</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">《颜料》</span><span style="font-size:9pt;"> 2008</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">月。</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">第</span><span style="font-size:9pt;">491</span><span style="font-size:9pt;font-family:宋体;">页。</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">化学工业出版社。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">崔春芳</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">项哲学</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">化工产品手册，第六版</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">《颜料》</span><span style="font-size:9pt;"> 2016</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">1</span><span style="font-size:9pt;font-family:宋体;">月。</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">第</span><span style="font-size:9pt;">466-7</span><span style="font-size:9pt;font-family:宋体;">页。</span><span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">同上</span><span style="font-size:9pt;"></span> <span style="font-size:9pt;"> </span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9pt;">Indanthrene Brown R </span></u></strong><span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">它应该是由英国人</span><span style="font-size:9pt;font-family:宋体;">，</span><span style="font-size:9pt;font-family:宋体;">译自德文</span><span style="font-size:9pt;font-family:宋体;">，</span><span style="font-size:9pt;font-family:宋体;">但未说明。</span><span style="font-size:9pt;"><span>     </span></span><span style="font-size:9pt;font-family:宋体;">抄自</span><span style="font-size:9pt;">BIOS 1493, 12-13.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Plant:</span></u></strong><span style="font-size:9pt;"><span>  </span>4000 litres iron vessel, steam jacket.<span>       </span></span><span style="font-size:9pt;">25000 litres tiled tank.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>       </span></span><span style="font-size:9pt;">12000 litres blowegg.<span>                </span><span>   </span>Wooden filter press.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Materials:</span></u></strong><span style="font-size:9pt;"><span>  </span>2700 kg. 96% sulphuric acid.<span>          </span>900 kg. 20% oleum.<span>    </span></span><br /> <p class="MsoNormal" style="text-indent:40.5pt;"> <span style="font-size:9pt;"><span> </span>675 kg. Indanthrene Brown R base.<span>     </span>45 kg. <strong><u>sodium chlorate</u></strong></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Method:</span></u></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">The Brown R base <strong>(= [128-89-2])</strong> is added to the mixture of sulphuric acid and oleum over 7-8 hours below 30<sup>0</sup>C.<span>  </span>Stirred till dissolved.<span>  </span>Blown to 7 cu. metre water in which is dissolved <strong><u>45 kg. sodium chlorate.</u></strong><span>  </span>Temperature rises to 60-65<sup>0</sup>C. Add further 45 kg <strong>sodium chlorate</strong>, heat with direct steam to 90-95<sup>0</sup>C.<span>  </span>Maintain 4 hours.<span>  </span>Dilute to 21 cu. metre, filtered and washed.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">Yield</span></u></strong><strong><span style="font-size:9pt;"> = 4129 kg.</span></strong><span style="font-size:9pt;"> paste at standard strength.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;"> </span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9pt;">Indanthrene Brown R Paste</span></u></strong><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">它应该是由美国人，译自德文，也未说明。</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">抄自</span><span style="font-size:9pt;">FIAT 1313,II, 106-107.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">反应式：</span></u></strong><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">本人有加注。<br /> <img alt="" src="data:image/png;base64,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" /></span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><span style="font-size:9pt;"></span><br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">In a 4000 liter steel kettle are placed 2700 kilograms sulfuric acid, 96%, and 900 kilograms oleum, 20%. With water cooling, in the course of the night, are added 675 kilograms of Indanthrene Brown R Base (<strong>= [12-89-2]</strong>) Ground, the temperature not being allowed to exceed 30<sup>0</sup>.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">The finished melt is then blown into a tub in which have been placed 45 kilograms <strong><u>sodium chlorate</u></strong> dissolved in 7 cubic meters of water. The length of time of blowing over is one to one and one-half hours. The final temperature reaches 60-65<sup>0</sup> and then 45 kilograms more <strong><u>sodium chlorate</u></strong> are added, heated with direct steam to 90-95<sup>0</sup> (by this is obtained acid of about 32%), the temperature being held for 4 hours.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">Following this the tank is filled with water to about 21 cubic meters by which the temperature falls to 50-55<sup>0</sup>. The contents of the tub are then sucked, in three parts, to a Montejus and is filtered off into three filter presses. The product is then washed with cold water to neutrality.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">Charge:</span></u></strong><strong><span style="font-size:9pt;"><span>  </span>675 </span></strong><span style="font-size:9pt;">kilograms <strong>Indanthrene Brown R Base,</strong> 62% =<strong> 418.5 </strong>Kilograms 100%</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">Yield:</span></u></strong><span style="font-size:9pt;"><span>  </span><strong>2753 </strong>kilograms plant product wet, 15% = 412.9 kilograms dry, 100% = <strong>4129</strong> kilograms paste type, 10%</span> <span style="font-size:9pt;"> </span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9pt;">Indanthrene Brown R</span></u></strong><span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">日本人，译自</span><span style="font-size:9pt;">FIAT 1313,II, 106-107.<span>              </span></span><span style="font-size:9pt;font-family:宋体;">抄自日文。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;">4 m<sup>2</sup> </span><span style="font-size:9pt;font-family:宋体;">の钢制釜に</span><span style="font-size:9pt;">96%</span><span style="font-size:9pt;font-family:宋体;">硫酸</span><span style="font-size:9pt;">2700 kg, 20%</span><span style="font-size:9pt;font-family:宋体;">发烟硫酸</span><span style="font-size:9pt;">900kg </span><span style="font-size:9pt;font-family:宋体;">を装入し夜间水て</span><span style="font-size:9pt;">”</span><span style="font-size:9pt;font-family:宋体;">冷しておきフ</span><span style="font-size:9pt;">”</span><span style="font-size:9pt;font-family:宋体;">ラウン</span><span style="font-size:9pt;">R</span><span style="font-size:9pt;font-family:宋体;">ヘ</span><span style="font-size:9pt;">”</span><span style="font-size:9pt;font-family:宋体;">スの粉末</span><span style="font-size:9pt;">675kg (62%) </span><span style="font-size:9pt;font-family:宋体;">を</span><span style="font-size:9pt;">30<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">以下て加え</span><span style="font-size:9pt;">7 h </span><span style="font-size:9pt;font-family:宋体;">搅拌の後水</span><span style="font-size:9pt;">7 t,<strong> <u>NaClO</u><sub>3</sub> <u>45 kg </u></strong></span><strong><u><span style="font-size:9pt;font-family:宋体;">の</span></u></strong><span style="font-size:9pt;font-family:宋体;">中<strong><u>に</u></strong></span><span style="font-size:9pt;">1 – 1<sup>1</sup>/<sub>2</sub> h</span><strong><u><span style="font-size:9pt;font-family:宋体;">を</span></u></strong><span style="font-size:9pt;font-family:宋体;">要<strong><u>して</u></strong>排出<strong><u>する</u></strong>。</span><span style="font-size:9pt;">60-65<sup>0</sup> </span><span style="font-size:9pt;font-family:宋体;">に上る。</span><span style="font-size:9pt;"> </span><strong><u><span style="font-size:9pt;">NaClO</span></u></strong><strong><sub><span style="font-size:9pt;">3</span></sub></strong><strong><span style="font-size:9pt;"> 45 kg</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">を追加し生蒸气て</span><span style="font-size:9pt;">”90-95<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">に上け</span><span style="font-size:9pt;">”4h</span><span style="font-size:9pt;font-family:宋体;">保温する。约</span><span style="font-size:9pt;">21m<sup>3</sup> </span><span style="font-size:9pt;font-family:宋体;">になるまて</span><span style="font-size:9pt;">”</span><span style="font-size:9pt;font-family:宋体;">水を加え</span><span style="font-size:9pt;">50-55<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">て</span><span style="font-size:9pt;">”</span><span style="font-size:9pt;font-family:宋体;">滤過し水洗する。</span><strong><span style="font-size:9pt;">412.9 kg </span></strong><span style="font-size:9pt;">(100%).</span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><u><span style="font-size:9pt;">C.I. </span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">颜料棕</span></u></strong><strong><u><span style="font-size:9pt;"> 28.</span></u></strong><span style="font-size:9pt;"><span>         </span></span><span style="font-size:9pt;font-family:宋体;">抄自《有机颜料品种及应用手册》</span><span style="font-size:9pt;"></span> <p class="MsoNormal"> <u><span style="font-size:9pt;font-family:宋体;">合成方法：</span></u><u><span style="font-size:9pt;"></span></u> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">将</span><span style="font-size:9pt;">675</span><span style="font-size:9pt;font-family:宋体;">公斤色基溶于</span><span style="font-size:9pt;">2700</span><span style="font-size:9pt;font-family:宋体;">公斤浓硫酸及</span><span style="font-size:9pt;">900</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">20%</span><span style="font-size:9pt;font-family:宋体;">的发烟硫酸中，温度</span><span style="font-size:9pt;">30<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">，在</span><span style="font-size:9pt;">2</span><span style="font-size:9pt;font-family:宋体;">小时内稀释到水中，加</span><strong><u><span style="font-size:9pt;">45</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">公斤氯化钠</span></u></strong><span style="font-size:9pt;font-family:宋体;">，加热至</span><span style="font-size:9pt;">90<sup>0</sup>C, </span><span style="font-size:9pt;font-family:宋体;">反应</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">小时。降温至</span><span style="font-size:9pt;">50<sup>0</sup>C, </span><span style="font-size:9pt;font-family:宋体;">过滤，水洗，经过特定的颜料化处理得颜料棕</span><span style="font-size:9pt;">28 </span><span style="font-size:9pt;font-family:宋体;">（己胺</span><span style="font-size:9pt;">BIOS1493</span><span style="font-size:9pt;font-family:宋体;">，</span><span style="font-size:9pt;">p. 10,12</span><span style="font-size:9pt;font-family:宋体;">）</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">《有机颜料化学及工艺学》相同，但未说明资料来源。</span><span style="font-size:9pt;"></span> <span style="font-size:9pt;"> </span> <p class="MsoNormal" style="text-indent:18pt;"> <strong><u><span style="font-size:9pt;">C.I. </span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">颜料棕</span></u></strong><strong><u><span style="font-size:9pt;"> 28</span></u></strong><span style="font-size:9pt;font-family:宋体;">。</span><span style="font-size:9pt;"><span>                                         </span></span><span style="font-size:9pt;font-family:宋体;">抄自</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">化工产品手册《颜料》第五版。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">将</span><span style="font-size:9pt;">675</span><span style="font-size:9pt;font-family:宋体;">公斤色基溶于</span><span style="font-size:9pt;">2700</span><span style="font-size:9pt;font-family:宋体;">公斤浓硫酸和</span><span style="font-size:9pt;">900</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">20%</span><span style="font-size:9pt;font-family:宋体;">的发烟硫酸中，控制溶解温度不高于</span><span style="font-size:9pt;">30<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">。然后在</span><span style="font-size:9pt;">1-2</span><span style="font-size:9pt;font-family:宋体;">小时内将其稀释到水中，加入</span><strong><u><span style="font-size:9pt;">45</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">公斤氯化钠</span></u></strong><span style="font-size:9pt;font-family:宋体;">，加热至</span><span style="font-size:9pt;">90<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">，反应</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">小时。反应完毕后，降温至</span><span style="font-size:9pt;">50<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">，过滤，水洗，经过特定的颜料化处理，得产品。</span><span style="font-size:9pt;"><span>  </span></span><strong><span style="font-size:9pt;font-family:宋体;">注：</span></strong><span style="font-size:9pt;font-family:宋体;">未说明资料来源，第六版相同。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">致读者：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">因为我未抄录德文原件，所以不能评述英文资料，其中</span><span style="font-size:9pt;">FIAT</span><span style="font-size:9pt;font-family:宋体;">比较详细。对照德文题目和英文译文，中文把氯酸钠</span><span style="font-size:9pt;">(<strong>Sodium chlorate</strong>), </span><span style="font-size:9pt;font-family:宋体;">写成<strong><u>氯化钠</u></strong>是不应该出现的差错，而且四本书都一样<strong>有错！</strong>一些小问题不在这里说了。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><span style="font-size:9pt;font-family:宋体;">按工艺，</span></strong><span style="font-size:9pt;font-family:宋体;">闭环得到产品是一种<strong>隐色体</strong>，有的容易氧化。有的不太容易氧化，需要加入<strong>氯酸钠</strong>作为氧化剂。<strong>氯化钠</strong>重复出现是否编者另有见解，那么氯化钠在这里起什么作用？</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">有错不怕，改过来就可以，问题是重复出现。当然写书比我不写书好多了，本人的化学文库只是把过去抄录的资料拿出来，供大家参考。也一定会有错，请大家指正。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">本人已多次联系出版社，就是无法直接与编者联系，讨论。我希望通过读者能联系到他们，如果可以，给个邮箱号，因为现在网上交流很方便，至少读者也可以了解我的意图。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">再有，一些德文原件只有北京有，如果有用，请读者提供未知可否？</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;"> </span> <span style="font-size:9pt;font-family:宋体;">本人邮箱：</span><strong><span style="font-size:9pt;">E-mail: tech-1@mhchem. Com</span></strong> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">陈忠源</span></strong><span style="font-size:9pt;"><span>  </span>2016</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">5</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">23</span><span style="font-size:9pt;font-family:宋体;">日</span><span style="font-size:9pt;"><span>                                             </span></span><span style="font-size:9pt;font-family:宋体;">于</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">无锡</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">明辉国际。</span><span style="font-size:9pt;"></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000134" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000134</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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