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CAS号 [128-89-2] 生产工艺 4,5-二苯甲酰氨基-1,1’-二蒽醌亚胺

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CAS号 [128-89-2] 生产工艺     4,5-二苯甲酰氨基-1,1’-二蒽醌亚胺
	
		CAS名:  Benzamide, N,N’-[iminobis(9,10-dihydro-9,10-dioxo-8,1-anthracenediyl)]bis- 
		
			生产工艺文献：  BIOS 1493, 12.  Indanthren Brown R dianthrimide. 
			
				FIAT 1313, 107.  Indanthrene Brown R Base Crude. 
				
					PB 25627, 2363-2366. Indanthrenbraun R Base.    1929年6月。以萘为溶剂。        未抄录。 
					
						PB 82232, 956-958.  Indanthrenbraun FFR.           
						
							用途：  C.I. 还原棕3 = C.I. 颜料棕28. 
							
								Indanthrene Brown R dianthrimide    英国人译自德文。                 抄自 BIOS 1493, 12. 
								
									Plant:  3000 litre enameled or coper vessel, oil jacket with steam coil 30 atm. steam.    3000 l. Venuleth. 
									
										       10000 l. tiled vessel.        Nutsch 65 sq. metre (tiled). 
										
											Materials:  2000 litres nitrobenzene.             190 kg. 1-amino-5-benzoylaminoanthraquinone. 
											
												          240 kg. 1-chloro-4-benzoylaminoanthraquinone.    50 kg. magnesia (MgO). 
												
													          145 kg sodium acetate.                         3.8 kg copper powder. 
													
														Method: 
														
															The above mixture is heated to 205-2100C., the copper powder being added at 1800C.  Stirred 3 hours at 205-2100C. then blown to Venuleth. Nitrobenzene distilled. Residue boiled with dilute HCl, filtered and washed. 
															
																Yield = 361 kg. 
																
																	  Indanthrene Brown R Paste         美国人译自德文。          抄自 FIAT 1313,II, 107.
																	
																		反应式：   本人有加注。 
<img alt="" src="http://www.陈忠源化学文库.cn//chenzhongyuan/Upload/ArticlePicture/IMG_24052016_104318.png" /> 
																		
																			This product was made at Leverkusen Plant as follows: 
																			
																				In anenamelled, agitated reaction kettle are placed 2000 liters of nitrobenzene and then are added 
																				
																					190 kilograms 1-amino-5benzoylamino anthraquinone.   240 kilograms 1-benzoylamino-4-chloro anthraquinone.       50 kilograms magnesium oxide.       145 kilograms sodium acetate (kesselsaltz) 
																					
																						This mixture is then agitated and heated to 205-2100 in about 5 hours and then cooled back to 1800 at which temperature 3.8 kilograms of copper powder are added. 
																						
																							At the end of three hours the condensation is finished and the melt is blown to a Venuleth and there the nitrobenzene is distilled off. The removal of inorganic salts is carried out by boiling the crude, dry ground product in dilute hydrochloric acid 2% in 8000 liters of water in a 10,000 liter brick lined extraction tank after which the crude is filtered off on a brick lined nutsch, washed with hot water, and dried. 
																							
																								Yield = 361 kilograms of plant product dry = 98% of theory. 
																								
																									中文译文，请见： 周春隆 穆振义 《有机颜料化学及工艺学》 2014年6月。 第748页。 
																									
																										                崔春芳 项哲学 化工产品手册 第六版 《颜料》 2016年1月。第466-457页。 
																										
																											陈忠源   2016年5月23日                          于 无锡  明辉国际。
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