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发 送 文 章     C.I. 溶剂紫2 (C.I. 16055 / 45170) 生产工艺 CAS号 [94277-70-0] [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <span><strong><u>C.I. </u></strong></span><strong><u><span style="font-family:宋体;">溶剂紫</span><span>2 (C.I. 16055 / 45170) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span> </u><span><span> </span>CAS</span></strong><strong><span style="font-family:宋体;">号</span><span> [94277-70-0]</span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">名</span></u></strong><strong><u><span style="font-size:9pt;">:</span></u></strong><strong><span style="font-size:9pt;"><span>  </span>Xanthylium, </span></strong><span style="font-size:9pt;">9-(2-carboxyphenyl)-3,6-bis(diethylamino)-,<span>  </span>[5-[(5-chloro-2-hydroxyphenyl)azo]-</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>      </span>-6-hydroxy-2-naphthalenesulfonato(3-)]<strong>hydroxychromate(1-)</strong></span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产工艺文献</span></u></strong><strong><u><span style="font-size:9pt;">:</span></u></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">PB 73561, 680.<span>   </span>Vorschrift zur Herstellung von Zaponechtviolett RR <span> </span></span></u></strong><u><span style="font-size:9pt;">1936</span></u><u><span style="font-size:9pt;font-family:宋体;">年月</span></u><u><span style="font-size:9pt;">27</span></u><u><span style="font-size:9pt;font-family:宋体;">日。</span></u><u><span style="font-size:9pt;font-family:宋体;">抄录如下。</span></u><u><span style="font-size:9pt;"></span></u> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">结构式：</span></u></strong><span style="font-size:9pt;"><span>   </span>Einsatz 1 / 20 kg Mol.<span>   </span></span><span style="font-size:9pt;font-family:宋体;">本人有加注。<br /> <img alt="" src="http://www.陈忠源化学文库.cn//chenzhongyuan/Upload/ArticlePicture/QQ图片20160801093522.png" /></span> <p class="MsoNormal"> <strong><span style="font-size:9pt;"><span> </span>120 kg </span></strong><span style="font-size:9pt;">Fw. <strong>Palatinechtviolett 3Rn </strong>warden in</span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;">2000 l. Kondenswasser von 75-80<sup>0</sup></span></strong><span style="font-size:9pt;"> geloest, das Palatinechtviolett muss vollstaendig in Loesung gehen, dann laesst man unter Ruehren auf etwas <strong>60<sup>0 </sup></strong>abkuehlen.<span>  </span>Zu dieser Loesung fliesst bei gutem Ruehren innerhalb <strong><sup>1</sup>/<sub>2</sub> Stunde </strong>folgende Loesung ein:</span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;">24 kg <span> </span>Rhodamin B </span></strong><span style="font-size:9pt;">extra (Hw) warden in</span> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;">1000 l. Kondenswasser von 70<sup>0</sup></span></strong><span style="font-size:9pt;"> geloest und dann mit wenig <strong>Eis </strong>auf <strong>60<sup>0</sup></strong> abgekuehlt. Nach beendetem Zulauf das <strong>Zaponechtviolett RR</strong> fast vollstaendig in kolloidalar Loesung. Die Abscheidung wird bewirkt durch rasches Zufliessenlassen von</span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;"><span> </span>200 l. Salzsaeure </span></strong><span style="font-size:9pt;">verd. Innerhalb <strong>5 Minuten. </strong>Sogleich bei Beginn des Zulaufs der Salzsaeure wird zweckmaessigerweise mit etwas <strong>Zaponechtviolett RR </strong>angeimpft, um von vornherein eine kristalline Abscheidung zu gewaehrleisten. (stark Kongosaure Reaktion). Uber Nacht geruehrt, dann mit</span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;">1500 l.<span>  </span>Wasser </span></strong><span style="font-size:9pt;">verduennt. Der Auslauf ist ganz schwach <strong>violett.</strong></span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;"><span>       </span></span></strong><span style="font-size:9pt;">Man presst ab.<span>  </span>Benoetig wird 1 Presse mitt 17 Rshmen<span>  </span>+<span>  </span>10 Rahmen. (76 x 92 x 3 cm)</span> <br /> <p class="MsoNormal" style="margin-left:30.85pt;text-indent:-30.85pt;"> <span style="font-size:9pt;"><span>       </span>Dauer des Fuellens einer Presse:</span> <br /> <p class="MsoNormal" style="margin-left:30.85pt;text-indent:-30.85pt;"> <span style="font-size:9pt;"><span>       </span>Gewicht des Presskuchens: <strong>280 – 300 kg.</strong></span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;"><span>       </span></span></strong><span style="font-size:9pt;">Auf Holzhorden oder Havegschalen bei <strong>40<sup>0</sup></strong> im Luftschrank getrocknet.</span> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><u><span style="font-size:9pt;">Ausbeute:</span></u></strong><span style="font-size:9pt;"><span>  </span>aus <strong>0.05 kg </strong>mol =<strong> 24 kg Rhodamin B </strong>extra <strong>= 73 kg Zaponechtviolett RR</strong></span> <br /> <p class="MsoNormal" style="margin-left:30.85pt;text-indent:-30.85pt;"> <span style="font-size:9pt;"><span>          </span>= 304% Betriebsausbeute</span> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><u><span style="font-size:9pt;">Reinfarbstoffgehalt:</span></u></strong><span style="font-size:9pt;"><span>  </span>95% Mol 1387 = 69 kg Reinfarbstoff =<strong> 100% der Theorie.</strong></span> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><u><span style="font-size:9pt;font-family:宋体;">译文仅供参考：</span></u></strong><strong><span style="font-size:9pt;"><span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">柴邦耐晒紫</span></strong><strong><span style="font-size:9pt;">RR</span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产工艺。</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="margin-left:25.7pt;text-indent:-25.7pt;"> <span style="font-size:7.5pt;"><span>    </span>120</span><span style="font-size:7.5pt;font-family:宋体;">公斤工业派拉丁耐晒紫</span><span style="font-size:7.5pt;">3RN </span><span style="font-size:7.5pt;font-family:宋体;">于</span><span style="font-size:7.5pt;">2000</span><span style="font-size:7.5pt;font-family:宋体;">公斤</span><span style="font-size:7.5pt;">75-78<sup>0</sup>C.</span><span style="font-size:7.5pt;font-family:宋体;">蒸馏水中，加热至完全溶解，然后冷至</span><span style="font-size:7.5pt;">60<sup>0</sup>C.</span><span style="font-size:7.5pt;font-family:宋体;">，在充分搅拌下，于半小</span><span style="font-size:7.5pt;"></span> <br /> <p class="MsoNormal" style="margin-left:25.7pt;text-indent:-25.7pt;"> <span style="font-size:7.5pt;font-family:宋体;">时内加入由</span><span style="font-size:7.5pt;">24</span><span style="font-size:7.5pt;font-family:宋体;">公斤罗丹明</span><span style="font-size:7.5pt;">B</span><span style="font-size:7.5pt;font-family:宋体;">和</span><span style="font-size:7.5pt;">1000</span><span style="font-size:7.5pt;font-family:宋体;">升蒸馏水，于</span><span style="font-size:7.5pt;">70<sup>0</sup>C.</span><span style="font-size:7.5pt;font-family:宋体;">溶解并冷至</span><span style="font-size:7.5pt;">60<sup>0</sup>C.</span><span style="font-size:7.5pt;font-family:宋体;">的溶液，由此得到的柴邦耐晒紫</span><span style="font-size:7.5pt;">RR</span><span style="font-size:7.5pt;font-family:宋体;">呈胶态状溶液，立</span><span style="font-size:7.5pt;"></span> <br /> <p class="MsoNormal" style="margin-left:25.7pt;text-indent:-25.7pt;"> <span style="font-size:7.5pt;font-family:宋体;">即在</span><span style="font-size:7.5pt;">5</span><span style="font-size:7.5pt;font-family:宋体;">分钟内加入</span><span style="font-size:7.5pt;">200</span><span style="font-size:7.5pt;font-family:宋体;">升稀盐酸，酸化到刚果红呈酸性析出，为确保析出良好，开始加酸时应加入先前的紫</span><span style="font-size:7.5pt;">RR</span><span style="font-size:7.5pt;font-family:宋体;">结晶，最后搅拌</span><span style="font-size:7.5pt;"></span> <br /> <p class="MsoNormal" style="margin-left:25.7pt;text-indent:-25.7pt;"> <span style="font-size:7.5pt;font-family:宋体;">过夜。第二天用</span><span style="font-size:7.5pt;">1500</span><span style="font-size:7.5pt;font-family:宋体;">升水稀释，取样润圈呈浅紫色，压滤。</span><span style="font-size:7.5pt;"> </span><span style="font-size:7.5pt;font-family:宋体;">以下：略。</span><span style="font-size:7.5pt;"></span> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><u><span style="font-size:9pt;font-family:宋体;">加注</span></u></strong><strong><u><span style="font-size:9pt;">:</span></u></strong><span style="font-size:9pt;"><span>  </span>1. </span><span style="font-size:9pt;font-family:宋体;">原版《染料索引》未提供参考文献。这类例子不少，以上仅供参考。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="margin-left:30.85pt;text-indent:-30.85pt;"> <span style="font-size:9pt;"><span>       </span>2. </span><span style="font-size:9pt;font-family:宋体;">按当时的资料，</span><span style="font-size:9pt;">C.I. </span><span style="font-size:9pt;font-family:宋体;">酸性紫</span><span style="font-size:9pt;">56</span><span style="font-size:9pt;font-family:宋体;">。未说明是</span><span style="font-size:9pt;">2:1</span><span style="font-size:9pt;font-family:宋体;">络合物，其实是</span><span style="font-size:9pt;">2:1</span><span style="font-size:9pt;font-family:宋体;">。以上仅供参考。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="margin-left:30.85pt;text-indent:-30.85pt;"> <span style="font-size:9pt;"><span>       </span>3. C.I. </span><span style="font-size:9pt;font-family:宋体;">溶剂紫</span><span style="font-size:9pt;">2</span><span style="font-size:9pt;font-family:宋体;">。其色号的</span><span style="font-size:9pt;">CAS</span><span style="font-size:9pt;font-family:宋体;">号是</span><strong><span style="font-size:9pt;">[61725-86-8]</span></strong><strong><span style="font-size:9pt;font-family:宋体;">。</span></strong><span style="font-size:9pt;font-family:宋体;">所以上述结构不一定正确。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="margin-left:30.85pt;text-indent:-30.85pt;"> <span style="font-size:9pt;"><span>       </span>4. </span><span style="font-size:9pt;font-family:宋体;">参见</span><span style="font-size:9pt;">C.I. </span><span style="font-size:9pt;font-family:宋体;">溶剂红</span><span style="font-size:9pt;">160</span><span style="font-size:9pt;font-family:宋体;">。</span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="margin-left:31pt;text-indent:-31pt;"> <strong><span style="font-size:9pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9pt;"><span>  </span></span></strong><span style="font-size:9pt;">2016</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">8</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">1</span><span style="font-size:9pt;font-family:宋体;">日</span><span style="font-size:9pt;"><span>              </span></span><span style="font-size:9pt;font-family:宋体;">于</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">无锡</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">明辉国际。</span><span style="font-size:9pt;"></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000206" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000206</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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