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CAS号 [10169-02-5]生产工艺- C.I.酸性红97(C.I. 22890)
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<p class="MsoNormal" align="center" style="text-align:center;"> CAS<span style="font-family:宋体;">号 </span><span style="font-family:Calibri;">[10169-02-5]</span><span style="font-family:宋体;">生产工艺</span>- C.I.<span style="font-family:宋体;">酸性红</span>97(C.I. 22890)<o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【</span>CAS<span style="font-family:宋体;">名</span><span style="font-family:宋体;">】</span><o:p></o:p> [1,1’-Biphenyl]-2,2’-disulfonic acid, 4,4’-bis[(2-hydroxy-1-naphthalenyl)azo]-disodium salt. Beil. 16. E<sup>2</sup>, 125.<o:p></o:p> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【</span><span style="font-family:宋体;">用途</span><span style="font-family:宋体;">】</span><span style="font-family:宋体;">织物染色，皮革，纸张的着色。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> BIOS 1548(=<span style="font-family:宋体;">胶卷</span><span style="font-family:Calibri;">PB 85593</span>), The manufacture of Azo and Lake Dyestuffs at Hoechst, Ludwigshafen and Leverkusen, 1946<span style="font-family:宋体;">年出版。</span><span style="font-family:Calibri;">BIOS 1548, 86. Acid Anthracene Red G (Leverksen).</span> <span style="font-family:宋体;">以下抄录文，本人有加注</span>：<o:p></o:p> <br /> <p class="MsoNormal"> Benzidine-2,2’-disulphonic acid [117-61-3](<span style="font-family:宋体;">已上传</span>) -->2 mol β-naphthol [135-19-3]<o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:21pt;"> 100kg Nitrite Benzindine-2,2’-disulphonic acid is dissolver at 50°C in 2,500L water with 90kg Na<sub>2</sub>CO<sub>3</sub><sub>, </sub>100kg NaNO<sub>2</sub> is added and the solution run into a mixture of 4,000L water, 350L HCl 19.5°Be’ and 675kg NaCl. Temperature 30°C. Volume 7,500L.<o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:21pt;"> 103kg Nitrite β-naphthol is dissolved at 80°C in 2,000L water with 60kg NaOH 100% (asliquor). Add 400 kg. Na<sub>2</sub>CO<sub>3</sub> and 2,000 kg. ice to cool to 10<sup>0</sup>C.<o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:21pt;"> Run in tetrazo during <sup>1</sup>/<sub>2</sub> hour. Heat to 65<sup>0</sup>C. and filter. Dry in vacuo at 90°C, and standardize with salt.<o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:21pt;"> Yield = 990kg. Type.<o:p></o:p> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【抄注】以上是英文，本人不再翻译。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> PB 74025, 1144. Säure anthracen Rot G =<span style="font-family:宋体;">英文</span><span style="font-family:Calibri;">Acid Anthracene Red G</span>, 1946<span style="font-family:宋体;">年，美国人公开的资料，本人未抄录。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> PB 82232. Production of dyes (BIOS Microfilm Reel F.D. 2537/46 (s.o.374/47) Frames 1 – 1057 A), 1939 – 1946, 1946<span style="font-family:宋体;">年美国公开。</span><o:p></o:p> <br /> <p class="MsoNormal"> PB 82232, 113. ‘Säure anthrscen rot G’, 1946. In German, <span style="font-family:宋体;">售价</span>2<span style="font-family:宋体;">美元</span>(<span style="font-family:宋体;">整卷</span>7<span style="font-family:宋体;">美元</span>)，<span style="font-family:宋体;">美国人介绍如下</span>：<o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:14.25pt;"> From Benzidine-2,2’-disulfonic acid and 2-Naphthol. <span style="font-family:宋体;">德文生产工艺，本人未抄录。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> ‘Colour Index’, Second Edition 1956<span style="font-family:宋体;">年</span>, P. 3164. C.I. 22890. C.I. Acid Red 97 (Bright yellowish Red).<o:p></o:p> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【结构式】略。</span><o:p></o:p> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【制法】</span>2,2’-Disulfobenzidine à 2-Naphthol (2 mol)<o:p></o:p> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【发明者】</span>Agfa 1886<span style="font-family:宋体;">年。</span><o:p></o:p> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【生产工艺参考文献】</span>BIOS 1548, 86. FIAT 764 – Säure anthrscen rot G. <span style="font-family:宋体;">书中未说明</span>FIAT 764 <span style="font-family:宋体;">是什么？也未提及利用方法。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">丁忠传主编《染料品种指南》。中国化工信息中心出版。</span>1995<span style="font-family:宋体;">年。</span>P.54, C.I. <span style="font-family:宋体;">酸性红</span>97(C.I. 22890). <span style="font-family:宋体;">【色调】</span>/<span style="font-family:宋体;">【结构式】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【制法】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【主要文献】均译自《</span><span style="font-family:Calibri;">Colour Index</span><span style="font-family:宋体;">》。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">杨新玮主编《世界染料品种</span>–2000<span style="font-family:宋体;">年》</span>，<span style="font-family:宋体;">沈阳化工研究院出版</span>, P.140, C.I.<span style="font-family:宋体;">酸性红</span>97(C.I. Acid Red 97, C.I. 22890)<span style="font-family:宋体;">。【结构式】</span>/<span style="font-family:宋体;">【色调】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【制法】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【参考文献】均译自</span>‘Colour Index’<span style="font-family:宋体;">。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">肖刚主编《世界染料品种</span>–2005<span style="font-family:宋体;">年》</span>，<span style="font-family:宋体;">全国染料工业信息中心出版</span>，2005<span style="font-family:宋体;">年</span>。P.72, C.I. <span style="font-family:宋体;">酸性红</span>97(C.I. Acid Red 97, C.I. 22890)<span style="font-family:宋体;">。【化学结构】</span>/<span style="font-family:宋体;">【制法】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【参考文献】均译自</span>‘Colour Index’<span style="font-family:宋体;">。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">第十三届全国染料与染色学术研讨会暨信息发布会</span>，2014<span style="font-family:宋体;">年</span>，P. 131-2，<span style="font-family:宋体;">浅析改善酸性染料溶解度的方法</span>（<span style="font-family:宋体;">李信</span>）。<span style="font-family:宋体;">笔者认为，</span>C.I. <span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">88</span><span style="font-family:宋体;">中残留的微量的乙萘酚类物是影响溶解度的主要因素。在合成过程中采用有效的方法，控制乙萘酚残留，不需要加助溶剂也可以得到溶解度</span><span style="font-family:Calibri;">50 g/L</span><span style="font-family:宋体;">以上的染料原粉。类似的现象也体现在</span><span style="font-family:Calibri;">C.I. </span><span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">97</span><span style="font-family:宋体;">，</span><span style="font-family:Calibri;">C.I. </span><span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">151</span><span style="font-family:宋体;">。</span><o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:15pt;"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">何岩彬主编《染料品种大全》</span>，<span style="font-family:宋体;">沈阳出版社出版</span>，2018<span style="font-family:宋体;">年</span>，P. 123-4, C.I. <span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">97 (C.I. Acid Red 97)</span><span style="font-family:宋体;">。【化学结构】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【色调】</span><span style="font-family:Calibri;">/</span><span style="font-family:宋体;">【制法】均译自《</span><span style="font-family:Calibri;">Colour Index</span><span style="font-family:宋体;">》。【参考文献】增加了本人免费提供的部分历史资料目录。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">【产品创新动态】</span>9<span style="font-family:宋体;">字头欧洲编号：</span><span style="font-family:Calibri;">914-973-2. = C.I. </span><span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">97 + C.I. </span><span style="font-family:宋体;">酸性黑</span><span style="font-family:Calibri;">234</span><span style="font-family:宋体;">；</span><span style="font-family:Calibri;">914-974-8. = C.I. </span><span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">97 + C.I. </span><span style="font-family:宋体;">酸性黑</span><span style="font-family:Calibri;">194</span><span style="font-family:宋体;">；</span><span style="font-family:Calibri;">914-975-3. = C.I. </span><span style="font-family:宋体;">酸性红</span><span style="font-family:Calibri;">97 + C.I. </span><span style="font-family:宋体;">酸性黑</span><span style="font-family:Calibri;">210</span><span style="font-family:宋体;">。</span>(<span style="font-family:宋体;">抄注：这类编号没有相应的</span>CAS<span style="font-family:宋体;">号</span>)。<o:p></o:p> <br /> <p class="MsoNormal" style="text-indent:14.25pt;"> <br /> <p class="MsoNormal"> 【寄语】<span style="font-family:宋体;">老有所为，力所能及，做点小事。</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /> <p class="MsoNormal"> <span style="font-family:宋体;">陈忠源</span> 2021<span style="font-family:宋体;">年</span><span style="font-family:Calibri;">8</span><span style="font-family:宋体;">月</span><span style="font-family:Calibri;">19</span><span style="font-family:宋体;">日</span>，<span style="font-family:宋体;">星期四</span><o:p></o:p> <br /> <p class="MsoNormal"> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10001620" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10001620</a>
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