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发 送 文 章     C.I. 颜料棕26（颜料紫29） [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容    <p class="MsoNormal"> <strong><span>C.I. </span></strong><strong><span style="font-family:宋体;">颜料棕</span><span> 26</span></strong><strong><span style="font-family:宋体;">（</span><span>C.I. 71129</span></strong><strong><span style="font-family:宋体;">）</span><span>= C.I. </span></strong><strong><span style="font-family:宋体;">颜料紫</span><span> 29<span>  </span><span>   </span>Pig. Br. 26.<span>  </span>CAS No.: [81-33-4]<br /> </span></strong><strong><span style="font-size:9pt;font-family:宋体;">反应式：<br /> <br /> <img alt="" src="http://www.陈忠源化学文库.cn//chenzhongyuan/Upload/ArticlePicture/clip_image002.gif" /><br /> </span></strong><strong><span style="font-family:宋体;">苝四甲酰二亚胺生产工艺规程</span><span><span>                      </span><span>                        </span>PB. 70057, 8580-3.</span></strong> <p class="MsoNormal"> <strong><span style="font-size:9pt;">Ludwigschafen = BASF </span></strong><strong><span style="font-size:9pt;font-family:宋体;">公司。</span></strong><strong><span style="font-size:9pt;"><span>                                              </span>1934</span></strong><strong><span style="font-size:9pt;font-family:宋体;">年</span></strong><strong><span style="font-size:9pt;">2</span></strong><strong><span style="font-size:9pt;font-family:宋体;">月</span></strong><strong><span style="font-size:9pt;">27</span></strong><strong><span style="font-size:9pt;font-family:宋体;">日</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:-18pt;"> <strong><span style="font-size:9pt;"><span>A.<span>       </span></span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产设备：</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoListParagraph" style="margin-left:36pt;text-indent:-18pt;"> <span style="font-size:9pt;"><span>1）<span>   </span></span></span><span style="font-size:9pt;font-family:宋体;">一台</span><span style="font-size:9pt;">1.5</span><span style="font-size:9pt;font-family:宋体;">立方米，含</span><span style="font-size:9pt;">0.5%</span><span style="font-size:9pt;font-family:宋体;">镍铁碱熔锅，配有锚式搅拌和挡板。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoListParagraph" style="margin-left:36pt;text-indent:-18pt;"> <span style="font-size:9pt;"><span>2）<span>   </span></span></span><span style="font-size:9pt;font-family:宋体;">一台</span><span style="font-size:9pt;">12</span><span style="font-size:9pt;font-family:宋体;">立方米，卧式铁稀释锅，搅拌转速</span><span style="font-size:9pt;">10</span><span style="font-size:9pt;font-family:宋体;">转</span><span style="font-size:9pt;">/</span><span style="font-size:9pt;font-family:宋体;">分，配有蒸汽加热和冷却用夹套。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoListParagraph" style="margin-left:36pt;text-indent:-18pt;"> <span style="font-size:9pt;"><span>3）<span>   </span></span></span><span style="font-size:9pt;font-family:宋体;">一台抽料用离心泵。</span><span style="font-size:9pt;"><span>       </span><span>       </span><span>  </span>4</span><span style="font-size:9pt;font-family:宋体;">）</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">一台铁压滤机</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">（</span><span style="font-size:9pt;">1000 x 1000 x 36</span><span style="font-size:9pt;font-family:宋体;">框）</span><span style="font-size:9pt;"></span> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:-18pt;"> <strong><span style="font-size:9pt;"><span>B.<span>       </span></span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">操作步骤：</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:0cm;"> <span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">1.5</span><span style="font-size:9pt;font-family:宋体;">立方米碱熔锅内，加入</span><strong><span style="font-size:9pt;">630</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">苛性钾和</span><strong><span style="font-size:9pt;">60</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">无水醋酸钠，加热熔融升温到</span><strong><span style="font-size:9pt;">210<sup>0</sup>C,</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">在约</span><strong><span style="font-size:9pt;">3</span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">小时内，</span></strong><span style="font-size:9pt;font-family:宋体;">加入</span><strong><span style="font-size:9pt;">200</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><strong><span style="font-size:9pt;">1,8-</span></strong><strong><span style="font-size:9pt;font-family:宋体;">萘二甲酰亚胺</span></strong><span style="font-size:9pt;font-family:宋体;">，再加热升温到</span><strong><span style="font-size:9pt;">220 – 225<sup>0</sup>C, </span></strong><span style="font-size:9pt;font-family:宋体;">并保温反应</span><strong><span style="font-size:9pt;">3</span></strong><strong><span style="font-size:9pt;font-family:宋体;">小时，</span></strong><span style="font-size:9pt;font-family:宋体;">因为熔融料很粘，难以抽料，所以在抽料前</span><span style="font-size:9pt;">1/4</span><span style="font-size:9pt;font-family:宋体;">小时内要加入</span><strong><span style="font-size:9pt;">60</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><strong><span style="font-size:9pt;">40<sup>0</sup></span></strong><span style="font-size:9pt;font-family:宋体;">波美液碱进行稀释，然后抽料到加有</span><strong><span style="font-size:9pt;">7</span></strong><strong><span style="font-size:9pt;font-family:宋体;">立方米水</span></strong><span style="font-size:9pt;font-family:宋体;">的</span><span style="font-size:9pt;">12</span><span style="font-size:9pt;font-family:宋体;">立方米稀释锅内，再喷入</span><strong><span style="font-size:9pt;">1</span></strong><strong><span style="font-size:9pt;font-family:宋体;">立方米热水，</span></strong><span style="font-size:9pt;font-family:宋体;">加热到</span><strong><span style="font-size:9pt;">100<sup>0</sup>C, </span></strong><span style="font-size:9pt;font-family:宋体;">并保温</span><strong><span style="font-size:9pt;">10</span></strong><strong><span style="font-size:9pt;font-family:宋体;">分钟，</span></strong><span style="font-size:9pt;font-family:宋体;">密闭设备，通入（</span><span style="font-size:9pt;">3</span><span style="font-size:9pt;font-family:宋体;">表压）压缩空气，将稀释后的<strong>隐色体氧化</strong></span><strong><span style="font-size:9pt;">16 – 20</span></strong><strong><span style="font-size:9pt;font-family:宋体;">小时，</span></strong><span style="font-size:9pt;font-family:宋体;">其间，每隔<strong>一小时，</strong>放压取样测终点，并重新压入空气氧化，如此取样到试样由<strong>棕色</strong>变<strong>红色，</strong>并不再变色为止。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">合格后，稀释锅内加冷水至满锅，在</span><strong><span style="font-size:9pt;">70 – 80<sup>0</sup>C </span></strong><span style="font-size:9pt;font-family:宋体;">压料到压滤机内进行压滤，用热水洗到中性。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;font-family:宋体;">得量：</span></strong><strong><span style="font-size:9pt;">194</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><strong><span style="font-size:9pt;"> = </span></strong><strong><span style="font-size:9pt;font-family:宋体;">收率</span></strong><strong><span style="font-size:9pt;"> 97%</span></strong><strong><span style="font-size:9pt;font-family:宋体;">。</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;"></span></strong><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">操作要点及不正常原因：</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:-18pt;"> <span style="font-size:9pt;"><span>1）<span>   </span></span></span><span style="font-size:9pt;font-family:宋体;">碱熔后，在抽料前，必须用碱液稀释，否则很难抽料，并会堵塞管道。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:-18pt;"> <span style="font-size:9pt;"><span>2）<span>   </span></span></span><span style="font-size:9pt;font-family:宋体;">加水煮沸后，应该通压缩空气彻底氧化，否则难于用来合成<strong>阴丹士林红</strong></span><strong><span style="font-size:9pt;">GG</span></strong><span style="font-size:9pt;font-family:宋体;">（译注：</span><strong><span style="font-size:9pt;">C.I. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">还原红</span></strong><strong><span style="font-size:9pt;">23 =</span></strong><span style="font-size:9pt;"></span> <br /> <p class="MsoListParagraph" style="margin-left:18pt;text-indent:0cm;"> <strong><span style="font-size:9pt;">C.I. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">颜料红</span></strong><strong><span style="font-size:9pt;">179</span></strong><span style="font-size:9pt;font-family:宋体;">），即难于甲基化，见实验报告</span><span style="font-size:9pt;"> Nr. 810<sup>a</sup> .</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;"></span></strong><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">生产控制分析：</span></strong><span style="font-size:9pt;font-family:宋体;">隐色体氧化，必须每隔一小时取样测终点，直到苝四甲酰亚胺的红色不变化为止。</span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">原料质量控制：</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;font-family:宋体;">见萘二甲酰亚胺生产工艺规程。</span><span style="font-size:9pt;"> <span>1934</span></span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">1</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">15</span><span style="font-size:9pt;font-family:宋体;">日</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">第</span><span style="font-size:9pt;">3</span><span style="font-size:9pt;font-family:宋体;">页。</span><span style="font-size:9pt;"> </span><strong><span style="font-size:9pt;font-family:宋体;">译注：</span></strong><strong><span style="font-size:9pt;"> PB. 70057, 8529 – 32.</span></strong><span style="font-size:9pt;"></span> <br /> <strong><span style="font-size:9pt;font-family:宋体;">成品质量控制：</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">在实验室合成<strong>阴丹士林红</strong></span><strong><span style="font-size:9pt;"> GG.</span></strong> <br /> <strong><span style="font-size:9pt;font-family:宋体;">生产周期及日生产能力：</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">约需</span><span style="font-size:9pt;">36 – 40</span><span style="font-size:9pt;font-family:宋体;">小时，每两天生产一批。</span><span style="font-size:9pt;"></span> <br /> <strong><span style="font-size:9pt;font-family:宋体;">注：</span></strong><strong><span style="font-size:9pt;">BIOS 1484, 21. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">摘</span></strong><span style="font-size:9pt;font-family:宋体;">译自德文，用的是英文。</span><span style="font-size:9pt;"></span> <br /> <strong><span style="font-size:9pt;font-family:宋体;"><br /> 明辉国际</span></strong><strong><span style="font-size:9pt;"> <span><span>  </span></span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;font-family:宋体;">译自</span><span style="font-size:9pt;"> <strong><span>PB. 70057, 8580-3 (</span></strong></span><strong><span style="font-size:9pt;font-family:宋体;">德文</span></strong><strong><span style="font-size:9pt;">).<span>  </span>E-mail: tech-1@mhchem.com<span>    </span>2015</span></strong><strong><span style="font-size:9pt;font-family:宋体;">年</span></strong><strong><span style="font-size:9pt;">7</span></strong><strong><span style="font-size:9pt;font-family:宋体;">月</span></strong><strong><span style="font-size:9pt;">28</span></strong><strong><span style="font-size:9pt;font-family:宋体;">日。</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <strong><span style="font-size:9pt;font-family:宋体;">译注：</span></strong><span style="font-size:9pt;">PB</span><span style="font-size:9pt;font-family:宋体;">报告至今未见有人引用，但</span><strong><span style="font-size:9pt;">BIOS 1484, 21. </span></strong><span style="font-size:9pt;font-family:宋体;">它是</span><strong><span style="font-size:9pt;">PB</span></strong><strong><span style="font-size:9pt;font-family:宋体;">报告</span></strong><span style="font-size:9pt;font-family:宋体;">的英译文，而且是摘译文，可能是书本印刷体的关系，至今仍有人引用。</span><strong><span style="font-size:9pt;">BIOS 1484,21 – Perylene tetracarboxylic acid diimide </span></strong><strong><span style="font-size:9pt;font-family:宋体;">的译文如下：</span></strong><strong><span style="font-size:9pt;"></span></strong> <p class="MsoNormal" style="margin-left:17.7pt;text-indent:-17.7pt;"> <strong><span style="font-size:9pt;font-family:宋体;">日文译文：</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;"> </span><strong><span style="font-size:9pt;font-family:宋体;">细田豊</span></strong><strong><span style="font-size:9pt;"> <span>– </span></span></strong><span style="font-size:9pt;font-family:宋体;">理论制造染料化学</span><span style="font-size:9pt;">- 1957</span><span style="font-size:9pt;font-family:宋体;">，</span><span style="font-size:9pt;">P. 738. No. 406. </span><span style="font-size:9pt;font-family:宋体;">列有<strong>引用文献。</strong></span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="margin-left:17.7pt;text-indent:-17.7pt;"> <strong><span style="font-size:9pt;font-family:宋体;">中文译文：</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;"> </span><strong><span style="font-size:9pt;font-family:宋体;">张澍声</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;">– </span><span style="font-size:9pt;font-family:宋体;">精细化工中间体工业生产技术</span><span style="font-size:9pt;">- 1996</span><span style="font-size:9pt;font-family:宋体;">年版和</span><span style="font-size:9pt;">2006</span><span style="font-size:9pt;font-family:宋体;">年版，<strong>分子式，结构式均错！</strong></span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="margin-left:17.7pt;text-indent:-17.7pt;"> <strong><span style="font-size:9pt;"><span>        </span></span></strong><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;"> </span><strong><span style="font-size:9pt;font-family:宋体;">项</span></strong><strong><span style="font-size:9pt;"><span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">斌</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;">– </span><span style="font-size:9pt;font-family:宋体;">颜料</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">（化工产品手册</span><span style="font-size:9pt;"> <span>– </span></span><span style="font-size:9pt;font-family:宋体;">第五版）</span><span style="font-size:9pt;">- 2008</span><span style="font-size:9pt;font-family:宋体;">年，</span><span style="font-size:9pt;">P.536-7</span><span style="font-size:9pt;font-family:宋体;">。未列<strong>文献出处。</strong></span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="margin-left:17.7pt;text-indent:-17.7pt;"> <strong><span style="font-size:9pt;"><span>        </span></span></strong><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;"> </span><strong><span style="font-size:9pt;font-family:宋体;">周春隆</span></strong><strong><span style="font-size:9pt;"> <span>–</span></span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">有机颜料品种及应用手册</span><span style="font-size:9pt;"> <span>– 2011</span></span><span style="font-size:9pt;font-family:宋体;">年，</span><span style="font-size:9pt;">P. 558.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">未列<strong>文献出处。</strong></span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal" style="margin-left:17.65pt;text-indent:-17.65pt;"> <span style="font-size:9pt;"><span>        </span></span><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;"> </span><strong><span style="font-size:9pt;font-family:宋体;">韩长日</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;">– </span><span style="font-size:9pt;font-family:宋体;">颜料生产技术</span><span style="font-size:9pt;"> <span>– 2014</span></span><span style="font-size:9pt;font-family:宋体;">年，</span><span style="font-size:9pt;">P. 231.<span>            </span></span><span style="font-size:9pt;font-family:宋体;">未列<strong>文献出处。</strong></span><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">专利引用：</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;font-family:宋体;">见</span><span style="font-size:9pt;"> <strong><span>US 6521756. </span></strong></span><strong><span style="font-size:9pt;font-family:宋体;">手册引用：</span></strong><span style="font-size:9pt;font-family:宋体;">世界染料品种</span><span style="font-size:9pt;"> <span>– 2005. P. 1155. - <strong>BIOS. PB. </strong></span></span><strong><span style="font-size:9pt;font-family:宋体;">两者</span></strong><span style="font-size:9pt;font-family:宋体;">均未引用。</span><span style="font-size:9pt;"></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000022" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000022</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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