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发 送 文 章     C.I. 还原蓝20合成工艺 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容    <p class="MsoNormal"> <strong><span><span>           </span><span> </span>C. I. </span></strong><strong><span style="font-family:宋体;">还原蓝</span><span>20 = C. I.</span></strong><strong><span style="font-family:宋体;">颜料蓝</span><span>65.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">（生产工艺）</span><span><span>       </span>CAS</span></strong><strong><span style="font-family:宋体;">号：</span><span>116-71-2</span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">CAS Name: </span></strong><span style="font-size:9pt;">Anthra[9,1,2-cde]benzo{rst}pentaphene-5,10-dione</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">发明人</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;"><span> </span>O. Bally and M. H. Isler.<span>  </span>1904</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">商品名</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;"><span> </span></span><span style="font-size:9pt;font-family:宋体;">还原深蓝</span><span style="font-size:9pt;"> BO</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">合成工艺路线</span></strong><strong><span style="font-size:9pt;">:<br /> <img alt="" src="http://www.陈忠源化学文库.cn//chenzhongyuan/Upload/ArticlePicture/IMG_18012016_105322.png" /><br /> </span></strong><span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <span></span><br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;">[82-05-3]<span>                          </span><span>  </span>[116-71-2]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">化学过程</span></strong><strong><span style="font-size:9pt;">:</span></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">苯绕蒽酮在无水醋酸钠存在下</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用钾</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">钠混合碱</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">于高温碱熔</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">二分子苯绕蒽酮</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">1, 2-</span><span style="font-size:9pt;font-family:宋体;">位缩合成紫蒽酮隐色体</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">最后经氧化成紫蒽酮</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">德国生产工艺汇编</span></strong><strong><span style="font-size:9pt;">:</span></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">还原蓝</span><span style="font-size:9pt;">20.<span>  </span>[116-71-2]<span>    </span></span><span style="font-size:9pt;font-family:宋体;">译自</span><strong><span style="font-size:9pt;">PB,</span></strong><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">报告</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">1.<span>  </span>1933<span style="font-family:宋体;"><span>年</span></span>4<span style="font-family:宋体;"><span>月</span></span>3<span style="font-family:宋体;"><span>日</span></span>. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产工艺</span></strong><strong><span style="font-size:9pt;">.<span>    </span></span></strong><span style="font-size:9pt;font-family:宋体;">译自</span><strong><span style="font-size:9pt;">PB. 25627. </span></strong><span style="font-size:9pt;">2802-2812. </span><span style="font-size:9pt;font-family:宋体;">（德文）</span><span style="font-size:9pt;"><span>                  </span>[116-71-2]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">操作步骤</span></strong><strong><span style="font-size:9pt;">:</span></strong><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">1.5</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;font-family:宋体;">配制锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">于半小时内加入</span><strong><span style="font-size:9pt;">500</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">含少量<strong>咔唑</strong>的蒽渣和</span><strong><span style="font-size:9pt;">240</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">精制<strong>苯绕蒽酮</strong></span><span style="font-size:9pt;"> (</span><span style="font-size:9pt;font-family:宋体;">纯度约</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;">85%) = 100% 200</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">. </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">120<sup>0</sup>C</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">熔化一小时</span><span style="font-size:9pt;">. </span><span style="font-size:9pt;font-family:宋体;">将熔化后的苯绕蒽酮</span><span style="font-size:9pt;">- </span><span style="font-size:9pt;font-family:宋体;">蒽渣在</span><span style="font-size:9pt;">1.5</span><span style="font-size:9pt;font-family:宋体;">小时内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">通过加热管道压料到碱溶锅内</span><span style="font-size:9pt;"> <span>(</span></span><span style="font-size:9pt;font-family:宋体;">用含镍</span><span style="font-size:9pt;">0.3%</span><span style="font-size:9pt;font-family:宋体;">的士林蓝</span><span style="font-size:9pt;">RS</span><span style="font-size:9pt;font-family:宋体;">碱熔锅</span><span style="font-size:9pt;">), </span><span style="font-size:9pt;font-family:宋体;">碱熔锅内予先加有熔化的</span><strong><span style="font-size:9pt;">400</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;">90%</span><strong><span style="font-size:9pt;font-family:宋体;">苛性钾</span></strong><span style="font-size:9pt;font-family:宋体;">和</span><strong><span style="font-size:9pt;">40</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤无水醋酸钠</span></strong><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">170 –175<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">开始受料</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">温度下降时用煤气火加热到</span><span style="font-size:9pt;">170<sup>0</sup>C</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">由于反应放热</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">温度自行升高到</span><strong><span style="font-size:9pt;">225 –230<sup>0</sup>C</span></strong><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">保持</span><span style="font-size:9pt;">1 – 1.5</span><span style="font-size:9pt;font-family:宋体;">小时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">放料到</span><span style="font-size:9pt;">1.6</span><span style="font-size:9pt;font-family:宋体;">立方米还原锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">锅内加有</span><span style="font-size:9pt;">6000</span><span style="font-size:9pt;font-family:宋体;">立升</span><span style="font-size:9pt;">54<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水和</span><span style="font-size:9pt;">75</span><span style="font-size:9pt;font-family:宋体;">公斤硅藻土</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">受料后升温到</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">立即用</span><strong><span style="font-size:9pt;">400</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤保险粉</span></strong><span style="font-size:9pt;font-family:宋体;">溶液</span><span style="font-size:9pt;"> (14 – 15%)</span><span style="font-size:9pt;font-family:宋体;">进行还原</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">1, </span><span style="font-size:9pt;font-family:宋体;">合格后立即过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">2, </span><span style="font-size:9pt;font-family:宋体;">滤饼用由</span><span style="font-size:9pt;">2500</span><span style="font-size:9pt;font-family:宋体;">立升</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水</span><span style="font-size:9pt;">, 48</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">43<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">波美液硷和</span><span style="font-size:9pt;">210</span><span style="font-size:9pt;font-family:宋体;">公斤保险粉溶液</span><span style="font-size:9pt;"> (14 – 15%)</span><span style="font-size:9pt;font-family:宋体;">洗</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">经</span><span style="font-size:9pt;">30 – 40</span><span style="font-size:9pt;font-family:宋体;">分钟后</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">再用由</span><span style="font-size:9pt;">4000</span><span style="font-size:9pt;font-family:宋体;">立升</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水</span><span style="font-size:9pt;">, 48</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">43<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">波美液碱和</span><span style="font-size:9pt;">210</span><span style="font-size:9pt;font-family:宋体;">公斤保险粉溶液</span><span style="font-size:9pt;"> (14 – 15%)</span><span style="font-size:9pt;font-family:宋体;">洗</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">然后再用</span><span style="font-size:9pt;">4000</span><span style="font-size:9pt;font-family:宋体;">立升</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水和</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">公斤无水碳酸钠的配制液洗到无染料为止</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">总滤液</span><span style="font-size:9pt;"> (</span><span style="font-size:9pt;font-family:宋体;">约</span><span style="font-size:9pt;">20</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;">), </span><span style="font-size:9pt;font-family:宋体;">氧化到染料完全析出</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">3, </span><span style="font-size:9pt;font-family:宋体;">过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤饼用</span><span style="font-size:9pt;">400</span><span style="font-size:9pt;font-family:宋体;">立升</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水和</span><span style="font-size:9pt;">30</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">43<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">波美碱液</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">洗到无<strong>羟基苯绕蒽酮</strong></span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">4, </span><span style="font-size:9pt;font-family:宋体;">滤饼于</span><span style="font-size:9pt;">24</span><span style="font-size:9pt;font-family:宋体;">立方米锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水调浆</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">加</span><span style="font-size:9pt;">40</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">96%</span><span style="font-size:9pt;font-family:宋体;">硫酸酸化</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">热水洗到中性</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">干燥</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">得<strong>紫蒽酮纯</strong></span><strong><span style="font-size:9pt;">G.</span></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">同样方法</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用<strong>升华苯绕蒽酮</strong>碱熔</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">得<strong>紫蒽酮纯</strong></span><strong><span style="font-size:9pt;">S.</span></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <strong><span style="font-size:9pt;font-family:宋体;">收率</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;font-family:宋体;">约得</span><span style="font-size:9pt;">156</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;font-family:宋体;">紫蒽酮纯</span><span style="font-size:9pt;">G = 78%</span><span style="font-size:9pt;font-family:宋体;">收率</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;"><span>        </span></span><span style="font-size:9pt;font-family:宋体;">得</span><span style="font-size:9pt;">140</span><span style="font-size:9pt;font-family:宋体;">公斤紫蒽酮纯</span><span style="font-size:9pt;">S = 70%</span><span style="font-size:9pt;font-family:宋体;">收率</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">2.<span>  </span>1934<span style="font-family:宋体;"><span>年</span></span>1<span style="font-family:宋体;"><span>月</span></span>22<span style="font-family:宋体;"><span>日</span></span>. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产工艺</span></strong><strong><span style="font-size:9pt;">.<span>    </span></span></strong><span style="font-size:9pt;font-family:宋体;">同上</span><span style="font-size:9pt;">.<span>                                     </span>[116-71-2]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">操作步骤</span></strong><strong><span style="font-size:9pt;">:<span>  </span></span></strong><span style="font-size:9pt;font-family:宋体;">基本同上</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">还原用水</span><span style="font-size:9pt;">10</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">硅藻土</span><span style="font-size:9pt;">100</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">操作要点</span></strong><strong><span style="font-size:9pt;">:</span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;"><span>    </span></span></strong><span style="font-size:9pt;font-family:宋体;">尽可能还原好</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用还原液洗涤时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">不要有间断</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">否则会影响收率</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">加苯绕蒽酮</span><span style="font-size:9pt;"> <span>– </span></span><span style="font-size:9pt;font-family:宋体;">蒽渣共熔物时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">碱液温度不要超过</span><span style="font-size:9pt;">160-165<sup>0</sup>C, </span><span style="font-size:9pt;font-family:宋体;">否则也会影响收率</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">如温度超过</span><span style="font-size:9pt;">200<sup>0</sup>C</span><span style="font-size:9pt;">,</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">收率会降到</span><span style="font-size:9pt;">55%, </span><span style="font-size:9pt;font-family:宋体;">低于</span><span style="font-size:9pt;">160<sup>0</sup>C</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">则碱要凝固</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>    </span></span><span style="font-size:9pt;font-family:宋体;">蒽渣的氮含量</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">不要大于</span><span style="font-size:9pt;">2.5% (</span><span style="font-size:9pt;font-family:宋体;">即含少量咔唑</span><span style="font-size:9pt;">), </span><span style="font-size:9pt;font-family:宋体;">其作用尚未明了</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">一部分是起平衡热效应作用</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">从而减少羟基苯绕蒽酮的生成</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">生产控制</span></strong><strong><span style="font-size:9pt;">:</span></strong> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">1. </span><span style="font-size:9pt;font-family:宋体;">过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤液为紫红色</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤饼中不再有紫蒽酮</span><span style="font-size:9pt;">.<span>  </span><span>       </span><span> </span></span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">2. </span><span style="font-size:9pt;font-family:宋体;">滤液过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">应无残渣</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">3. </span><span style="font-size:9pt;font-family:宋体;">氧化完全</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤液应清</span><span style="font-size:9pt;">.<span>      </span></span><br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">4. </span><span style="font-size:9pt;font-family:宋体;">碱洗后的滤饼取样</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">在试验室酸化</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">使羟基紫蒽酮的钠盐酸析出来</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">洗到无酸性</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">再用稀碱液共煮</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">过滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤液只微微出现羟基苯绕蒽酮的黄色荧光</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">原料苯绕蒽酮</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;font-family:宋体;">精制品</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">含量</span><span style="font-size:9pt;">: 85%;<span>   </span></span><span style="font-size:9pt;font-family:宋体;">升华品</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">含量</span><span style="font-size:9pt;">: 100%</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">生产周期</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">废料</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">碱熔记录图</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">3.<span>  </span>1939<span style="font-family:宋体;"><span>年</span></span>4<span style="font-family:宋体;"><span>月</span></span>24<span style="font-family:宋体;"><span>日</span></span>. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产工艺</span></strong><strong><span style="font-size:9pt;">.<span>    </span></span></strong><span style="font-size:9pt;"><span>    </span><strong>PB. 25628. </strong>3883-3887.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">（英文）</span><span style="font-size:9pt;"><span>            </span>[116-71-2]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;"><span>    </span></span></strong><span style="font-size:9pt;font-family:宋体;">基本是</span><span style="font-size:9pt;">PB</span><span style="font-size:9pt;font-family:宋体;">报告的英文摘译</span><span style="font-size:9pt;">.<span>  </span>Grasselli N. J.<span>     </span></span><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">4.<span>  </span>1939<span style="font-family:宋体;"><span>年</span></span>9<span style="font-family:宋体;"><span>月</span></span>13<span style="font-family:宋体;"><span>日</span></span>. </span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产工艺</span></strong><strong><span style="font-size:9pt;">.<span>    </span></span></strong><span style="font-size:9pt;font-family:宋体;">译自</span><strong><span style="font-size:9pt;">PB. 73726. </span></strong><span style="font-size:9pt;">176-182.<span>    </span></span><span style="font-size:9pt;font-family:宋体;">（德文）</span><span style="font-size:9pt;"><span>            </span>[116-71-2]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">化学过程</span></strong><strong><span style="font-size:9pt;">:</span></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">同前</span><span style="font-size:9pt;">. </span><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">理论投得量</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;"><span> </span>200<span style="font-family:宋体;"><span>公斤</span></span>(100%) </span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 198.3<span style="font-family:宋体;"><span>公斤</span></span>.<span>          </span>100<span style="font-family:宋体;"><span>公斤</span></span>(100%) </span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 99.1<span style="font-family:宋体;"><span>公斤</span></span></span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">实际投得量</span></strong><strong><span style="font-size:9pt;">:<span>  </span></span></strong><span style="font-size:9pt;">200</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;"> (100%) </span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 156 <span style="font-family:宋体;"><span>公斤</span></span><span>           </span>100<span style="font-family:宋体;"><span>公斤</span></span>(100%) </span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"> 78 <span style="font-family:宋体;"><span>公斤</span></span>.<span>     </span></span><strong><span style="font-size:9pt;font-family:宋体;">收率</span></strong><strong><span style="font-size:9pt;">: 78.7%</span></strong><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">生产周期及日产量</span></strong><strong><span style="font-size:9pt;">:<span>  </span></span></strong><span style="font-size:9pt;font-family:宋体;">每批约需</span><span style="font-size:9pt;"> 36 – 40</span><span style="font-size:9pt;font-family:宋体;">小时</span><span style="font-size:9pt;">.<span>   </span></span><span style="font-size:9pt;font-family:宋体;">日产两批</span><span style="font-size:9pt;">, =312<span style="font-family:宋体;"><span>公斤</span></span><span style="font-family:宋体;">紫蒽酮</span>.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">生产设备</span></strong><strong><span style="font-size:9pt;">:<span>  </span></span></strong><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">操作步骤</span></strong><strong><span style="font-size:9pt;">:</span></strong><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">1.5</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;font-family:宋体;">化料锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">于</span><span style="font-size:9pt;">45</span><span style="font-size:9pt;font-family:宋体;">分钟内细心地加入</span><strong><span style="font-size:9pt;">500</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">含少量咔唑的<strong>蒽渣</strong>和</span><strong><span style="font-size:9pt;">240</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">精制<strong>苯绕蒽酮</strong></span><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <span style="font-size:9pt;">(</span><span style="font-size:9pt;font-family:宋体;">纯度约</span><span style="font-size:9pt;">85%) = 200</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">, 100%. </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">120<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">熔化一小时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">1.5</span><span style="font-size:9pt;font-family:宋体;">小时内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">通过带筛网的加热管道</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">放料到碱熔锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">碱熔锅内予先加有</span><strong><span style="font-size:9pt;">600</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤钾</span></strong><strong><span style="font-size:9pt;">, </span></strong><strong><span style="font-size:9pt;font-family:宋体;">钠</span></strong><span style="font-size:9pt;font-family:宋体;">混合碱</span><span style="font-size:9pt;"> (96%, </span><span style="font-size:9pt;font-family:宋体;">平均组成为</span><span style="font-size:9pt;">67 – 68% <strong>KOH, </strong>27 – 28% <strong>NaOH</strong>, 3 – 4%</span><strong><span style="font-size:9pt;font-family:宋体;">水</span></strong><span style="font-size:9pt;">, 1% <strong>NaCO<sub>3</sub></strong>, </span><span style="font-size:9pt;font-family:宋体;">其余为</span><span style="font-size:9pt;">Fe<sub>2</sub>O<sub>3</sub></span><span style="font-size:9pt;font-family:宋体;">和</span><span style="font-size:9pt;"> KCl), (</span><span style="font-size:9pt;font-family:宋体;">它与士林蓝</span><span style="font-size:9pt;">RSN</span><span style="font-size:9pt;font-family:宋体;">碱熔相同</span><span style="font-size:9pt;">). </span><span style="font-size:9pt;font-family:宋体;">和</span><strong><span style="font-size:9pt;">50</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤无水醋酸钠</span></strong><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">180<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">受料</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">锅温下降时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用煤气火加热到</span><span style="font-size:9pt;">190<sup>0</sup>C</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">到温仃煤气加热</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">由于反应热</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">自行升温到</span><span style="font-size:9pt;">225 –230<sup>0</sup>C, </span><span style="font-size:9pt;font-family:宋体;">保温</span><span style="font-size:9pt;">1 – 1.5</span><span style="font-size:9pt;font-family:宋体;">小时</span><span style="font-size:9pt;"> (</span><span style="font-size:9pt;font-family:宋体;">可用煤气</span><span style="font-size:9pt;">), </span><span style="font-size:9pt;font-family:宋体;">保温完毕</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">放料到还原锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">锅内予先加有</span><strong><span style="font-size:9pt;">10</span></strong><strong><span style="font-size:9pt;font-family:宋体;">立方米</span></strong><span style="font-size:9pt;">54<sup>0</sup>C</span><strong><span style="font-size:9pt;font-family:宋体;">热水</span></strong><span style="font-size:9pt;font-family:宋体;">和</span><strong><span style="font-size:9pt;">100</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤硅藻土</span></strong><strong><span style="font-size:9pt;"> </span></strong><span style="font-size:9pt;">(</span><span style="font-size:9pt;font-family:宋体;">硅藻土予先在</span><span style="font-size:9pt;">0.5</span><span style="font-size:9pt;font-family:宋体;">立方米配制锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">加</span><span style="font-size:9pt;">200</span><span style="font-size:9pt;font-family:宋体;">立升水调配好</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">而后放到还原锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">它主要是使滤饼疏松</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">容易过滤和起料</span><span style="font-size:9pt;">), </span><span style="font-size:9pt;font-family:宋体;">在连续搅拌下受碱熔料</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">温度自动升高到</span><span style="font-size:9pt;">68<sup>0</sup>C</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用</span><strong><span style="font-size:9pt;">500</span></strong><strong><span style="font-size:9pt;font-family:宋体;">公斤保险粉</span></strong><span style="font-size:9pt;font-family:宋体;">溶液</span><span style="font-size:9pt;"> (14 – 15%)</span><span style="font-size:9pt;font-family:宋体;">进行还原</span><span style="font-size:9pt;">, (</span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">1), </span><span style="font-size:9pt;font-family:宋体;">合格后于</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">过滤</span><span style="font-size:9pt;"> (</span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">2), </span><span style="font-size:9pt;font-family:宋体;">压滤</span><span style="font-size:9pt;">10</span><span style="font-size:9pt;font-family:宋体;">分钟后</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤饼用空白还原液冲洗</span><span style="font-size:9pt;">. </span><span style="font-size:9pt;font-family:宋体;">空白还原液在硷熔锅内配制</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">其组成为</span><span style="font-size:9pt;">: <strong>2500</strong></span><strong><span style="font-size:9pt;font-family:宋体;">立升</span></strong><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水</span><span style="font-size:9pt;">,<strong> 48</strong></span><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;">43<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">波美氢氧化钠</span><span style="font-size:9pt;">,<strong> 210</strong></span><strong><span style="font-size:9pt;font-family:宋体;">公斤</span></strong><span style="font-size:9pt;font-family:宋体;">保险粉溶液</span><span style="font-size:9pt;"> (14 – 15%), </span><span style="font-size:9pt;font-family:宋体;">还原液冲洗时间约</span><span style="font-size:9pt;">45 – 60</span><span style="font-size:9pt;font-family:宋体;">分钟</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">洗完</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">再用下面二种空白还原液洗涤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">先是用</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;">60<sup>)</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水</span><span style="font-size:9pt;">,48<span style="font-family:宋体;"><span>公斤</span></span>43<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">波美氢氧化钠和</span><span style="font-size:9pt;">210</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;font-family:宋体;">保险粉溶液</span><span style="font-size:9pt;"> (14 – 15%), </span><span style="font-size:9pt;font-family:宋体;">配成的空白还原液</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">然后用</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水和</span><span style="font-size:9pt;">4</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;font-family:宋体;">无水碳酸钠配成的溶液洗涤到滤液中</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">不再有染料为止</span><span style="font-size:9pt;"> (</span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">3).</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">全部滤液于氧化锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">通空气氧化到染料完全析出</span><span style="font-size:9pt;"> (</span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">4), </span><span style="font-size:9pt;font-family:宋体;">时间约需</span><span style="font-size:9pt;">0.5 – 1</span><span style="font-size:9pt;font-family:宋体;">小时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">物料用离心泵打到压滤机内压滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤饼先用</span><span style="font-size:9pt;">8</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;font-family:宋体;">水和</span><span style="font-size:9pt;">30</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">43<sup>0</sup></span><span style="font-size:9pt;font-family:宋体;">波美碱配成的碱液洗</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">然后用</span><span style="font-size:9pt;">60 –65<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水洗到滤液不再有羟基苯绕蒽酮为止</span><span style="font-size:9pt;">. (</span><span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">5). </span><span style="font-size:9pt;font-family:宋体;">滤液于</span><span style="font-size:9pt;">24</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;font-family:宋体;">酸化锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">先用</span><span style="font-size:9pt;">3000</span><span style="font-size:9pt;font-family:宋体;">立方米</span><span style="font-size:9pt;">60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">热水调浆</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">然后用</span><span style="font-size:9pt;">40</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">96%</span><span style="font-size:9pt;font-family:宋体;">硫酸酸化</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">再经木压滤机压滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用热水洗掉酸性</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">滤饼即为<strong>紫蒽酮纯</strong></span><strong><span style="font-size:9pt;">G</span></strong><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">送</span><span style="font-size:9pt;">230#</span><span style="font-size:9pt;font-family:宋体;">车间加工商品化</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">它用于士林绿</span><span style="font-size:9pt;">3B, </span><span style="font-size:9pt;font-family:宋体;">黑</span><span style="font-size:9pt;">BGA, </span><span style="font-size:9pt;font-family:宋体;">黑</span><span style="font-size:9pt;">BB, </span><span style="font-size:9pt;font-family:宋体;">直接黑</span><span style="font-size:9pt;">RB</span><span style="font-size:9pt;font-family:宋体;">和海军蓝</span><span style="font-size:9pt;">BF</span><span style="font-size:9pt;font-family:宋体;">等</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">生产要点及生产控制</span></strong><strong><span style="font-size:9pt;">:<span>  </span></span></strong><span style="font-size:9pt;font-family:宋体;">见前</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">取样</span><span style="font-size:9pt;">5. </span><span style="font-size:9pt;font-family:宋体;">取滤液于试管中</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">应为十分弱的荧光和非常浅的黄色</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">5.<span>  </span>FIAT. 1313. II. 108-107.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">生产工艺</span></strong><strong><span style="font-size:9pt;">. </span></strong><span style="font-size:9pt;font-family:宋体;">略</span><span style="font-size:9pt;">.<span>     </span></span><span style="font-size:9pt;font-family:宋体;">（英文）</span><span style="font-size:9pt;"><span>                            </span>[116-71-2]</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;font-family:宋体;">它译自德文，但未说明资料来源。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">6.<span>  </span>BIOS 987. 75.<span>   </span></span></strong><span style="font-size:9pt;font-family:宋体;">它只是英文工艺摘要。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;"><span>          </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">附录</span></strong><strong><span style="font-size:9pt;">.</span></strong><span style="font-size:9pt;"><span>  </span>1975</span><span style="font-size:9pt;font-family:宋体;">年天津染化九厂生产工艺</span><span style="font-size:9pt;">.<span>                           </span>[116-71-2]</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">1.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">脱水</span></strong><strong><span style="font-size:9pt;">: </span></strong><span style="font-size:9pt;"><span> </span></span><span style="font-size:9pt;font-family:宋体;">精萘</span><span style="font-size:9pt;"><span>   </span>250</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">.<span>     </span></span><span style="font-size:9pt;font-family:宋体;">苯绕蒽酮</span><span style="font-size:9pt;"><span>   </span>100</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;"> (100%</span><span style="font-size:9pt;font-family:宋体;">计</span><span style="font-size:9pt;">)</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">脱水锅内加萘</span><span style="font-size:9pt;">250</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">苯绕蒽酮</span><span style="font-size:9pt;">100</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">升温脱水</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">在</span><span style="font-size:9pt;">90<sup>0</sup>C</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">盘车开搅拌</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">升温到</span><span style="font-size:9pt;">110<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">脱水完毕</span><span style="font-size:9pt;">,</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">准备併锅</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">一般脱水须</span><span style="font-size:9pt;">4 – 6</span><span style="font-size:9pt;font-family:宋体;">小时</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">2.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">化碱</span></strong><strong><span style="font-size:9pt;">:</span></strong><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">醋酸钠</span><span style="font-size:9pt;"><span>  </span>50</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">.<span>    </span></span><span style="font-size:9pt;font-family:宋体;">苛性钾</span><span style="font-size:9pt;"><span>  </span>190</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">.<span>     </span></span><span style="font-size:9pt;font-family:宋体;">苛性钠</span><span style="font-size:9pt;"><span>  </span>80</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">在化碱锅内</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">加入醋酸钠</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">苛性钾</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">苛性钠</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用热油升温化碱</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">升温至</span><span style="font-size:9pt;">190 –200<sup>0</sup>C, </span><span style="font-size:9pt;font-family:宋体;">盘车开搅拌</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">升温至</span><span style="font-size:9pt;">220<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">併锅</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="margin-left:18pt;text-indent:-18pt;"> <strong><span style="font-size:9pt;"><span>3.<span>        </span></span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">碱熔</span></strong><strong><span style="font-size:9pt;">:</span></strong> <br /> <p class="MsoNormal" style="margin-left:18pt;"> <span style="font-size:9pt;font-family:宋体;">用</span><span style="font-size:9pt;">2</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;font-family:宋体;">压力氮气</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">将脱水锅物料压出</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">併锅完毕</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用热油升温到</span><span style="font-size:9pt;">240 –250<sup>0</sup>C, </span><span style="font-size:9pt;font-family:宋体;">保温</span><span style="font-size:9pt;">1.5 – 2.0</span><span style="font-size:9pt;font-family:宋体;">小时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">压</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;font-family:宋体;">力</span><span style="font-size:9pt;">1.5 –2<span style="font-family:宋体;"><span>公斤</span></span>, </span><span style="font-size:9pt;font-family:宋体;">压力高于</span><span style="font-size:9pt;">2.5</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">放空于脱水锅</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">蒸萘</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">蒸完</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">由碱熔锅底部放料</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">4.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">稀释</span></strong><strong><span style="font-size:9pt;">:</span></strong><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal" style="text-indent:18pt;"> <span style="font-size:9pt;font-family:宋体;">稀释锅内加水</span><span style="font-size:9pt;">1000</span><span style="font-size:9pt;font-family:宋体;">立升</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">煮沸</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">用</span><span style="font-size:9pt;">2</span><span style="font-size:9pt;font-family:宋体;">公斤</span><span style="font-size:9pt;font-family:宋体;">压力压料到稀释锅</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">洗锅一次</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">合并</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">煮沸一小时</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">吹萘</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal" style="margin-left:18pt;text-indent:-18pt;"> <strong><span style="font-size:9pt;"><span>4.<span>        </span></span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">压滤</span></strong><strong><span style="font-size:9pt;">:</span></strong> <br /> <p class="MsoNormal" style="margin-left:18pt;"> <span style="font-size:9pt;font-family:宋体;">于</span><span style="font-size:9pt;">45 –60<sup>0</sup>C</span><span style="font-size:9pt;font-family:宋体;">压滤</span><span style="font-size:9pt;">, </span><span style="font-size:9pt;font-family:宋体;">热水洗至中性</span><span style="font-size:9pt;">.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">其它参考工艺：</span></strong><strong><span style="font-size:9pt;"></span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;"></span></strong><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">1.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">天津染料工艺汇编。</span></strong><span style="font-size:9pt;">212-3.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">还原深蓝</span><span style="font-size:9pt;">BO. (1980).</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;">2.<span>  </span></span></strong><strong><span style="font-size:9pt;font-family:宋体;">上海染料工艺汇编。</span></strong><span style="font-size:9pt;">413-4.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">还原深蓝</span><span style="font-size:9pt;">BO. (1976).</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <span style="font-size:9pt;"></span><br /> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">编注：</span></strong><span style="font-size:9pt;font-family:宋体;">原版</span><span style="font-size:9pt;"> Colour Index </span><span style="font-size:9pt;font-family:宋体;">和</span><span style="font-size:9pt;"> </span><span style="font-size:9pt;font-family:宋体;">世界染料品种</span><span style="font-size:9pt;"> <span>– 2005</span></span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">均未有</span><span style="font-size:9pt;">PB</span><span style="font-size:9pt;font-family:宋体;">报告报导！</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>      </span></span><span style="font-size:9pt;font-family:宋体;">不去了解，这么知道您有哪些创新点？</span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000035" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000035</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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