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发 送 文 章     C.I.颜料黄16 (C.I. 20040) 生产工艺 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <span><strong><u>C.I.</u></strong></span><strong><u><span style="font-family:宋体;">颜料黄</span><span>16 (C.I. 20040) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span> </u><span>CAS</span></strong><strong><span style="font-family:宋体;">号</span><span>: [5979-28-2]</span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">CAS</span></u></strong><strong><u><span style="font-size:9.0pt;font-family:宋体;">名：</span></u></strong><strong><span style="font-size:9.0pt;"><span>  </span>Butanamide, </span></strong><span style="font-size:9.0pt;">N,N’-(3,3’-dimethyl[1,1’-biphenyl]-4,4’-diyl)bis[2-[(2,4-dichlorophenyl)azo]-3-oxo-</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">发明者：</span></u></strong><span style="font-size:9.0pt;"><span>  </span>A. Laska and A. Zitscher <span> </span>1921</span><span style="font-size:9.0pt;font-family:宋体;">年。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">生产工艺文献：</span></u></strong><span style="font-size:9.0pt;"><span>  </span><strong>BIOS 1661</strong>, 144 (=PB 91693, 144) </span><span style="font-size:9.0pt;font-family:宋体;">英文，二手资料。</span><strong><span style="font-size:9.0pt;">Permanent Yellow NCG.<span>  </span></span></strong><span style="font-size:9.0pt;font-family:宋体;">见下。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>         </span><strong>FIAT 764 – Permanentgelb NGG (</strong>error <strong>for NCG)<span>     </span>Colour Index <span> </span></strong></span><span style="font-size:9.0pt;font-family:宋体;">未说明</span><span style="font-size:9.0pt;">PB</span><span style="font-size:9.0pt;font-family:宋体;">号。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9.0pt;"><span>         </span>FIAT 1313,III, </span></strong><span style="font-size:9.0pt;">473-5. </span><span style="font-size:9.0pt;font-family:宋体;">英文，二手资料。</span><strong><span style="font-size:9.0pt;">Permanent Yellow NCG.<span> </span></span></strong><span style="font-size:9.0pt;font-family:宋体;">见抄录文。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>         </span><strong>PB 74067, </strong>667-9. </span><span style="font-size:9.0pt;font-family:宋体;">德文，工艺摘要。非生产工艺原件。</span><span style="font-size:9.0pt;"><span> </span></span><span style="font-size:9.0pt;font-family:宋体;">未抄录。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>         </span><strong>PB 74123,</strong> 5920-5927. <strong>Permanentgelb NCG. </strong></span><span style="font-size:9.0pt;font-family:宋体;">德文，<strong>生产工艺</strong>工艺原件。</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">未抄录。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>         </span><strong>PB 74753. Pa – Po </strong></span><strong><span style="font-size:9.0pt;font-family:宋体;">商品名</span></strong><span style="font-size:9.0pt;font-family:宋体;">，品种卡片。有加工配方。</span><span style="font-size:9.0pt;"><span> </span></span><span style="font-size:9.0pt;font-family:宋体;">未抄录。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span>     </span></span><span style="font-size:9.0pt;font-family:宋体;">上海染料生产工艺汇编。</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">永固黄</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">。</span><span style="font-size:9.0pt;">1976</span><span style="font-size:9.0pt;font-family:宋体;">年。</span><span style="font-size:9.0pt;"> p. 478-479.<span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">请见原件。</span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;font-family:宋体;">项</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">斌</span><span style="font-size:9.0pt;"><span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">高建荣</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">编：化工产品手册，第五版“颜料”</span><span style="font-size:9.0pt;">2008</span><span style="font-size:9.0pt;font-family:宋体;">年。</span><span style="font-size:9.0pt;"> Bb 014. P. 188-190.<span> </span></span><span style="font-size:9.0pt;font-family:宋体;">见下。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;font-family:宋体;">化学工业出版社</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">出版：<strong>中国化工产品大全</strong>，第四版</span><span style="font-size:9.0pt;"> </span><span style="font-size:9.0pt;font-family:宋体;">“有机颜料”</span><span style="font-size:9.0pt;"> 2012</span><span style="font-size:9.0pt;font-family:宋体;">年。</span><span style="font-size:9.0pt;"> Fl 0014. P. 766.<span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">见下。</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">参考工艺：</span></u></strong><span style="font-size:9.0pt;"><span>   </span></span><span style="font-size:9.0pt;font-family:宋体;">上海染料生产工艺汇编。</span><span style="font-size:9.0pt;"><span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">永固黄</span><span style="font-size:9.0pt;">7G</span><span style="font-size:9.0pt;font-family:宋体;">。</span><span style="font-size:9.0pt;"> p. 473-475. </span><span style="font-size:9.0pt;font-family:宋体;">其重氮组分是<strong>对氯苯胺。</strong></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">永固黄</span></u></strong><strong><u><span style="font-size:9.0pt;">(C.I. </span></u></strong><strong><u><span style="font-size:9.0pt;font-family:宋体;">颜料</span></u></strong><strong><u><span style="font-size:9.0pt;">16 ) </span></u></strong><strong><u><span style="font-size:9.0pt;font-family:宋体;">生产工艺</span></u></strong><strong><u><span style="font-size:9.0pt;"> <span></span></span></u></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">颜料：</span></u></strong><span style="font-size:9.0pt;"><span>  </span>p. 189. </span><strong><span style="font-size:9.0pt;font-family:宋体;">【制法】</span></strong><span style="font-size:9.0pt;font-family:宋体;">译自</span><strong><span style="font-size:9.0pt;">BIOS 1661, </span></strong><span style="font-size:9.0pt;">144. </span><span style="font-size:9.0pt;font-family:宋体;">有错！如，</span><span style="font-size:9.0pt;">10 Kg. </span><span style="font-size:9.0pt;font-family:宋体;">活性炭，变成</span><strong><span style="font-size:9.0pt;">110 kg. </span></strong><span style="font-size:9.0pt;font-family:宋体;">活性炭。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><span> </span>580 L </span><span style="font-size:9.0pt;font-family:宋体;">冰醋酸，变成</span><strong><span style="font-size:9.0pt;">58 L </span></strong><span style="font-size:9.0pt;font-family:宋体;">冰醋酸，等。我已在书评</span><span style="font-size:9.0pt;"> <span>– 1</span></span><span style="font-size:9.0pt;font-family:宋体;">中说了。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="margin-left:65.85pt;text-indent:-65.85pt;"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">中国化工大全：</span></u></strong><span style="font-size:9.0pt;"><span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">第四版，上册。</span><span style="font-size:9.0pt;"> <span>P. 766. </span></span><span style="font-size:9.0pt;font-family:宋体;">【制法】<strong>错误，</strong>同上。这二本书，都未注明资料来自何处，为什么？不明白。至少我是知道的，它不是新资料，无非？不说了。留给读者看吧！</span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;">  <strong>FIAT 1313,III, </strong>473-475<span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">英译文，它比</span><strong><span style="font-size:9.0pt;">BIOS1661, </span></strong><span style="font-size:9.0pt;">144. </span><span style="font-size:9.0pt;font-family:宋体;">详细，但也不是原生产工艺，今抄录如下：供参考。</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9.0pt;">d.<span>  </span><u>The I.G. Farbenindustrie Processes:</u></span></strong> <br /> <p class="MsoNormal"> <strong><span style="font-size:9.0pt;">i.<span>  </span><u>Hoechst:</u><span>   </span><u>Permanent Yellow NCG Powder</u></span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Trade Name:</span></u></strong><strong><span style="font-size:9.0pt;"><span>  </span>Permanentgelb NCG Pulver (Hoe.)</span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Composition:</span></u></strong><span style="font-size:9.0pt;"><span>   </span></span><span style="font-size:9.0pt;font-family:宋体;">本人有加注。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><img src="data:image/png;base64,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" alt="" /></span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;">2:4-dichloroaniline<span>  </span></span><span style="font-size:9.0pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9.0pt;"><span>  </span>Naphthol AS-G<span>    </span></span><span style="font-size:9.0pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9.0pt;"> </span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Principal Uses:</span></u></strong><span style="font-size:9.0pt;"><span>  </span>Yellow pigment fast to overlacquering (lacquer solvents).</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Batch Size:</span></u></strong><span style="font-size:9.0pt;"><span>  </span>2 Mol.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Process:<br /> </span></u></strong><strong style="line-height:1.5;"><span style="font-size:9.0pt;"><u>Diazotization</u></span></strong><span style="font-size:9pt;line-height:1.5;">    </span><span style="font-size:9pt;line-height:1.5;font-family:宋体;">原译文，按德文格式，我把它连着写了。<br />  </span><span style="font-size:9pt;text-indent:18pt;line-height:1.5;">324 kg. 2:4-dichloroaniline are pasted the day before diazotization with 1000 l. H</span><sub style="text-indent:18pt;">2</sub><span style="font-size:9pt;text-indent:18pt;line-height:1.5;">O and 1700 l. HCl 5N. After heating to 80</span><sup style="text-indent:18pt;">0</sup><span style="font-size:9pt;text-indent:18pt;line-height:1.5;">C. it is stirred overnight. Next A.M. it is cooled with ice to 0</span><sup style="text-indent:18pt;">0</sup><span style="font-size:9pt;text-indent:18pt;line-height:1.5;">C; then 262 l. NaNO</span><sub style="text-indent:18pt;">2</sub><span style="font-size:9pt;text-indent:18pt;line-height:1.5;"> 40% by volume are run in under the surface, first quite rapidly then later more slowly. Should show a slightly positive test for nitrous acid on diphenyl sulfone paper and this should still remain after 1 hour stirring. The rather turbid diazo solution is clarified.</span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;"><strong><u>Solution & Precipitation of NAS – G<br /> </u></strong></span> <br /> <div style="text-indent:0px;display:inline !important;"> <span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  5000 l. H</span><sub style="font-weight:normal;text-indent:18pt;">2</sub><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">O are run into coupling vat 400 kg. Naphthol AS-G (pretested, for solubility in NaOH) are added and stirred 1/2 hour.</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">340 l. NaOH 33% by volume are added and the NAS-G stirred to solution. Volume is made with ice and H</span><sub style="font-weight:normal;text-indent:18pt;">2</sub><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">O to</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">18,000 l. at 7</span><sup style="font-weight:normal;text-indent:18pt;">0</sup><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">C.</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">50 kg. “Emulphor FM oil soluble” * prepared by stirring with a Hoerschagitator in</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">200 l. H</span><sub style="font-weight:normal;text-indent:18pt;">2</sub><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">O of 30</span><sup style="font-weight:normal;text-indent:18pt;">0</sup><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">C. is then added.</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">355 l. NaOH 33% is added and then the NAS-G precipitated with</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">580 l. Acetic acid 100%. The temperature rises to 11-12</span><sup style="font-weight:normal;text-indent:18pt;">0</sup><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">C. and the suspension should be positive to “deltasaurer” (See BIOS Report). The suspension is stirred for 1/4 hour.</span> </div> <p class="MsoNormal"> <span style="font-size:9.0pt;"><strong><u>Coupling<br /> </u></strong></span> <br /> <div style="text-indent:0px;display:inline !important;"> <span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">  The dazo solution is run thru a clarification press directly to the NAS-G under the surface over a period of 2 hours. Simultaneously a solution of  25 kg. </span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;font-family:宋体;">“</span><span style="font-size:9pt;font-weight:normal;line-height:1.5;text-indent:18pt;">Emulphor O * (Emulphor O should not be added to diazo solution because it smeare the press cloths, etc.) is added. The coupling shows free diazo. The product is then heated over 1 hour to 40<sup>0</sup>C. whereby coupling is completed. Then tested with R Salt solution, stirred 1/2 hour, and filtered, washed well, and dried at 55<sup>0</sup>C.</span> </div> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Yield: </span></u></strong><span style="font-size:9.0pt;"><span>   </span>800 kg.=247% of original weight of 2,4-dichloroaniline.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;">Notes:</span></u></strong><span style="font-size:9.0pt;"><span>  </span>With a good quality of NAS-G precipitation can be accomplished by use of<span>  </span>900 kg. NaAcetate and 800 l. HCl 5N in place of acetic acid after addition of the Emulphor FM by adding the NaAc and then the HCl.<br />  </span><span style="font-size:9pt;text-indent:17.25pt;line-height:1.5;">*Emulphor FM oil soluble = triethanolamine oleic acid ester.<br />  </span><span style="text-indent:17.25pt;font-size:9pt;line-height:1.5;">*Emulphor O = oxethylated oleyl alcohol. </span><span style="text-indent:17.25pt;font-size:9pt;line-height:1.5;font-family:宋体;">加注：其</span><span style="text-indent:17.25pt;font-size:9pt;line-height:1.5;">CAS</span><span style="text-indent:17.25pt;font-size:9pt;line-height:1.5;font-family:宋体;">号</span><span style="text-indent:17.25pt;font-size:9pt;line-height:1.5;">: [9004-98-2]<br />  </span><span style="font-family:宋体;font-size:9pt;text-indent:17.25pt;line-height:1.5;">上述译文，应是德文工艺摘要的英文摘译文，所以我说是二手货。</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9.0pt;font-family:宋体;">加注：</span></u></strong><span style="font-size:9.0pt;"><span>  </span></span><span style="font-size:9.0pt;font-family:宋体;">我以前的译文中，提到</span><span style="font-size:9.0pt;"> <strong><span>Le. = Le</span></strong><span>verkusen </span></span><span style="font-size:9.0pt;font-family:宋体;">厂。</span><span style="font-size:9.0pt;"> <span>= Bayer </span></span><span style="font-size:9.0pt;font-family:宋体;">公司。<br />  </span><span style="text-indent:-117pt;font-size:9pt;line-height:1.5;font-family:宋体;">它的生产工艺规程：</span><strong style="text-indent:-117pt;line-height:1.5;"><span style="font-size:9.0pt;">A. </span></strong><span style="text-indent:-117pt;font-size:9pt;line-height:1.5;">Chemischer Teil;  Konstitution;  Einsatz;  Ausbeute;  <strong>Arbeitsweise;</strong>  Erfahrengen.</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9.0pt;"><span>    </span><strong>B. <span> </span></strong>Technischer Teil;<span>  </span>Apparatur.</span> <br /> <p class="MsoNormal"> <span style="font-size:9.0pt;font-family:宋体;">文中，</span><strong><span style="font-size:9.0pt;">Hoechst.</span></strong><strong><span style="font-size:9.0pt;font-family:宋体;">公司</span></strong><strong><span style="font-size:9.0pt;"> = Hoe.<span>  </span></span></strong><span style="font-size:9.0pt;font-family:宋体;">因我过去主要研究酸性染料和还原染料，所以有机<strong>颜料</strong>未抄录原件。</span><span style="font-size:9.0pt;"></span> <br /> <p class="MsoNormal" style="margin-left:100.45pt;text-indent:-100.45pt;"> <strong><span style="font-size:9.0pt;"><span>    </span></span></strong><span style="font-size:9.0pt;font-family:宋体;">它的生产工艺规程：</span><strong><span style="font-size:9.0pt;">I. </span></strong><span style="font-size:9.0pt;">Einsatz.<span>  </span><strong>II. </strong>Ausbeute. <strong><span> </span>III. </strong>Kapazitaet. <strong><span> </span>IV. </strong><span> </span><strong>Verfahren.<span>  </span>V.<span>  </span></strong>Apparatur.<span>        </span><strong>VI. <span> </span></strong>Eigenschften.<span>  </span><strong>VII. <span> </span></strong>Chemische und Technische Aufgabe<span>  </span><strong><span> </span>VIII.<span>  </span></strong>Verwendung.</span> <br /> <p class="MsoNormal" style="margin-left:100.5pt;"> <strong><span style="font-size:9.0pt;">IX.<span>  </span>Betriebsproben.</span></strong> <br /> <p class="MsoNormal" style="text-indent:0px;"> <strong style="text-indent:17.25pt;line-height:1.5;"><span style="font-size:9pt;">  </span><span style="font-size:9.0pt;font-family:宋体;">上述二手资料，</span></strong><span style="text-indent:17.25pt;font-size:9pt;line-height:1.5;font-family:宋体;">还多次出版，为什么，比它详细得多的资料，无人用？</span> <br /> <p class="MsoNormal"> <strong><span style="font-size:9.0pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9.0pt;"><span>      </span></span></strong><span style="font-size:9.0pt;">2016</span><span style="font-size:9.0pt;font-family:宋体;">年</span><span style="font-size:9.0pt;">3</span><span style="font-size:9.0pt;font-family:宋体;">月</span><span style="font-size:9.0pt;">28</span><span style="font-size:9.0pt;font-family:宋体;">日。</span><span style="font-size:9.0pt;"></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000085" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000085</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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