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发 送 文 章     C.I. 直接红75 (C.I. 25380) 生产工艺 CAS号 [2829-43-8] [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p class="MsoNormal"> <span><strong><u>C.I. </u></strong></span><strong><u><span style="font-family:宋体;">直接红</span><span>75 (C.I. 25380) </span></u></strong><strong><u><span style="font-family:宋体;">生产工艺</span> </u><span><span>   </span>CAS</span></strong><strong><span style="font-family:宋体;">号</span><span> [2829-43-8]</span></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">CAS</span></u></strong><strong><u><span style="font-size:9pt;font-family:宋体;">名</span></u></strong><strong><u><span style="font-size:9pt;">:</span></u></strong><strong><span style="font-size:9pt;"><span>  </span>2-Naphthalenesulonic acid,</span></strong><span style="font-size:9pt;"> 5,5’-[carbonylbis[imino(2-sulfo-4,1-phenylene)azo]]bis[6-amino-</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>      </span>-4-hydroxy-, tetrasodium salt.<span>  </span></span><strong><u><span style="font-size:9pt;font-family:宋体;">发明者</span></u></strong><strong><span style="font-size:9pt;font-family:宋体;">：</span></strong><span style="font-size:9pt;">M. Ulrich and C. Heidenreich<span>  </span>1900</span><span style="font-size:9pt;font-family:宋体;">年。</span><span style="font-size:9pt;"></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">生产工艺文献：</span></u></strong><strong><u><span style="font-size:9pt;"></span></u></strong> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">PB 25625,</span></u></strong><u><span style="font-size:9pt;"> 831.<span>   </span><strong>Siriusrosa 2 B</strong><span>   </span>1935</span></u><u><span style="font-size:9pt;font-family:宋体;">年</span></u><u><span style="font-size:9pt;">2</span></u><u><span style="font-size:9pt;font-family:宋体;">月</span></u><u><span style="font-size:9pt;"> </span></u><u><span style="font-size:9pt;font-family:宋体;">生产工艺。</span></u><u><span style="font-size:9pt;font-family:宋体;">未抄录。</span></u> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">PB 25627,</span></u></strong><u><span style="font-size:9pt;"> 3247-50. <span> </span><strong>Fast Light Red 4BA </strong></span></u><u><span style="font-size:9pt;font-family:宋体;">（</span></u><u><span style="font-size:9pt;">C.I. </span></u><u><span style="font-size:9pt;font-family:宋体;">酸性红</span></u><u><span style="font-size:9pt;">34</span></u><u><span style="font-size:9pt;font-family:宋体;">）生产及光气化。</span></u><u><span style="font-size:9pt;">1937</span></u><u><span style="font-size:9pt;font-family:宋体;">年</span></u><u><span style="font-size:9pt;">2</span></u><u><span style="font-size:9pt;font-family:宋体;">月。</span></u><u><span style="font-size:9pt;font-family:宋体;">未抄录。</span></u><u><span style="font-size:9pt;"></span></u> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">PB 74025</span></u></strong><u><span style="font-size:9pt;">, 1667-8.<span>  </span><strong>Verfahren zur Herstellung von Siriusrosa BB. <span> </span></strong></span></u><u><span style="font-size:9pt;font-family:宋体;">抄录如下。</span></u><u><span style="font-size:9pt;"></span></u> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">反应式：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">本人有加注。路线</span><span style="font-size:9pt;">1</span><span style="font-size:9pt;font-family:宋体;">和路线</span><span style="font-size:9pt;">2.<br /> <img alt="" src="http://www.陈忠源化学文库.cn//chenzhongyuan/Upload/ArticlePicture/QQ图片20160720093837.png" /></span> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Konstitution:</span></u></strong><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">这是路线</span><span style="font-size:9pt;">1.</span> <br /> <p class="MsoNormal" style="text-indent:17.25pt;"> <span style="font-size:9pt;">4,4‘-Diamino=diphenylharnstoff-3,3‘-disulfosaeure –> </span><span style="font-size:9pt;font-family:Wingdings;"><span>à</span></span><span style="font-size:9pt;"><span> </span>2<span>  </span>Gammasaeure.</span> <p class="MsoNormal" style="text-indent:17.25pt;"> <strong><span style="font-size:9pt;">60 kg. </span></strong><span style="font-size:9pt;">Nitrit 4,4‘-Diamino-diphenylharnstoff-3,3‘-disulfosaeure ( Mol 402 = 138 Nitrit) werden in <strong>1000 l. </strong>Wasser uber Nacht cerruehrt. Morgen werden <strong>360 l. </strong>Salzsaeure <strong>19.5<sup>0</sup>Be‘</strong> zugegeben. Nachdem die Temperatur auf <strong>20<sup>0</sup></strong> gestellt ist, wird mit <strong>60 kg. </strong>Natriumnitrit 100% in 30%iger Loesung diazotiert. <strong>Volime 2000 l. Temperatur 25-30<sup>0</sup></strong> kurz vor Kuppels wird die Reaktion mit ca. <strong>50 kg. Soda </strong>schwach kongoviolett gestellt. <strong>61.5 kg. </strong>Nitrit Gammasaeure werden in <strong>2000 l. Wasser</strong> mit Natronlauge neutral geloest. Man mit <strong>500 kg. </strong>Eis auf <strong>0<sup>0</sup> </strong>gekuehlt. Die Diazotierung lauf in die obige Gammasaeureloesung. Gleich hinterher werden <strong>170 kg. </strong>Natriumacetat 100% in 20%iger Loesung zugegeben und danach <strong>100 kg. </strong>Natriumbicarbonat rein langsam eingesetzt. Temperatur <strong>10<sup>0</sup>. </strong>Nach <strong>2</strong> Stunden auf <strong>20<sup>0</sup></strong> anwaermen. Die Kupplung ruehrt <strong>46</strong> Stunden bei <strong>20<sup>0</sup></strong>. Sie wird auf <strong>50<sup>0</sup></strong> angewaermt und <strong>1</strong> Stunde bei <strong>50<sup>0</sup></strong> gehalten. Nun mit <strong>150 kg Soda </strong>alkalisch machen und mit <strong>25% </strong>Steinsalz bezogen auf Volumen aussalzen.<span>  </span><strong>Volumen ca. 6000 l.</strong></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Ausbeute:</span></u></strong><span style="font-size:9pt;"> ca. <strong>640 kg </strong>trocken <strong>990 kg </strong>Typ = 16.5 fache von Einsatz <strong>kg </strong>Nitrit<span>  </span>4,4‘=Diamino-diphenylharnstoff-3,3‘- </span><span style="font-size:9pt;">-disulfosaeure.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Trocken:</span></u></strong><span style="font-size:9pt;"><span>  </span>Vakuumschrank bei <strong>95<sup>0</sup>.</strong></span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">Einstellung:</span></u></strong><span style="font-size:9pt;"><span>  </span>Steinsalz.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;">PB 82232, </span></u></strong><u><span style="font-size:9pt;">635-6.<span> </span><strong>Siriusrosa BB.<span>  </span></strong></span></u><u><span style="font-size:9pt;font-family:宋体;">生产工艺。</span></u><u><span style="font-size:9pt;">1946</span></u><u><span style="font-size:9pt;font-family:宋体;">年。</span></u><u><span style="font-size:9pt;"><span> </span></span></u><u><span style="font-size:9pt;font-family:宋体;">未抄录。</span></u><u><span style="font-size:9pt;"></span></u> <br /> <p class="MsoNormal"> <u><span style="font-size:9pt;font-family:宋体;">日文摘译。</span></u><u><span style="font-size:9pt;font-family:宋体;">细田豊。</span></u><u><span style="font-size:9pt;font-family:宋体;">《<strong>理论制造染料化学</strong>》</span></u><u><span style="font-size:9pt;"><span>  </span>1957</span></u><u><span style="font-size:9pt;font-family:宋体;">年。</span></u><u><span style="font-size:9pt;"><span>  </span>P. 621-2. </span></u><u><span style="font-size:9pt;font-family:宋体;">请见原书。</span></u><u><span style="font-size:9pt;"></span></u> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">国内动态：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">化工技术资料</span><span style="font-size:9pt;"> 1966</span><span style="font-size:9pt;font-family:宋体;">年，</span><span style="font-size:9pt;">3, 54-5. </span><span style="font-size:9pt;font-family:宋体;">直接耐晒桃红</span><span style="font-size:9pt;">BK</span><span style="font-size:9pt;font-family:宋体;">试制情况简介</span><span style="font-size:9pt;"> <span>– </span></span><span style="font-size:9pt;font-family:宋体;">路线</span><span style="font-size:9pt;">2.</span> <br /> <p class="MsoNormal"> <span style="font-size:9pt;"><span>       </span></span><span style="font-size:9pt;font-family:宋体;">染料工业</span><span style="font-size:9pt;"> 1998</span><span style="font-size:9pt;font-family:宋体;">年，</span><span style="font-size:9pt;">3, 7-9.<span>  </span></span><span style="font-size:9pt;font-family:宋体;">非光气法合成直接耐晒桃红</span><span style="font-size:9pt;">BK</span><span style="font-size:9pt;font-family:宋体;">的研究</span><span style="font-size:9pt;"> <span>– </span></span><span style="font-size:9pt;font-family:宋体;">路线</span><span style="font-size:9pt;">2.</span> <br /> <p class="MsoNormal"> <strong><u><span style="font-size:9pt;font-family:宋体;">加注：</span></u></strong><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">上述生产工艺是路线</span><span style="font-size:9pt;">1</span><span style="font-size:9pt;font-family:宋体;">。原版</span><span style="font-size:9pt;">Colour Index </span><span style="font-size:9pt;font-family:宋体;">只有</span><span style="font-size:9pt;"> <strong><span>FIAT 764 – Siriusrosa BB.<span>  </span></span></strong></span><span style="font-size:9pt;font-family:宋体;">未列资料目录。</span><span style="font-size:9pt;"></span> <p class="MsoNormal"> <strong><span style="font-size:9pt;font-family:宋体;">陈忠源</span></strong><strong><span style="font-size:9pt;"><span>  </span></span></strong><span style="font-size:9pt;">2016</span><span style="font-size:9pt;font-family:宋体;">年</span><span style="font-size:9pt;">7</span><span style="font-size:9pt;font-family:宋体;">月</span><span style="font-size:9pt;">19</span><span style="font-size:9pt;font-family:宋体;">日</span><span style="font-size:9pt;"><span>         </span></span><span style="font-size:9pt;font-family:宋体;">于</span><span style="font-size:9pt;"><span>  </span></span><span style="font-size:9pt;font-family:宋体;">无锡</span><span style="font-size:9pt;"><span>   </span></span><span style="font-size:9pt;font-family:宋体;">明辉国际。</span><span style="font-size:9pt;"></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000195" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000195</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

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