[会员中心]    [设为主页][加入收藏][发布文章]  [中文繁體]

[选项] 文章类别： (全部)书评CAS和EC编号合成工艺函授 搜索选项：  全字匹配  空格分隔  文章编号  文章标题  文章作者  文章来源  相关链接  关键字词  文章标签  文章内容

首页 书评 CAS和EC编号 合成工艺 函授 问答 会员登录

文 库 搜 索 [选项] 文章类别： (全部)书评CAS和EC编号合成工艺函授 搜索选项：  全字匹配  空格分隔  文章编号  文章标题  文章作者  文章来源  相关链接  关键字词  文章标签  文章内容

发 送 文 章     CAS号 [3748-67-6] 生产工艺 3-乙酰氨基-4-甲氧基苯磺酰氯 [留言][评论][收藏] 收信地址     填写收信人的电子邮箱 邮件主题     填写邮件主题 邮件内容  <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;text-align:center;"> <span style="margin:0px;padding:0px;font-size:12px;">                  CAS<span style="margin:0px;padding:0px;font-family:宋体;">号</span> [3748-67-6] <span style="margin:0px;padding:0px;font-family:宋体;">生产工艺</span>     3-<span style="margin:0px;padding:0px;font-family:宋体;">乙酰氨基</span>-4-<span style="margin:0px;padding:0px;font-family:宋体;">甲氧基苯磺酰氯</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">CAS<span style="margin:0px;padding:0px;font-family:宋体;">名</span>: Benzenesulfonyl chloride, 3-(acetylamino)-4-methoxy-,    <span style="margin:0px;padding:0px;font-family:宋体;">历史参考文献：待检索。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">用途</span>: <span style="margin:0px;padding:0px;font-family:宋体;">有机合成。</span> C.I.<span style="margin:0px;padding:0px;font-family:宋体;">冰染重氮组分</span>14, 31, 42<span style="margin:0px;padding:0px;font-family:宋体;">。</span> LookChem<span style="margin:0px;padding:0px;font-family:宋体;">网登录生产与经营单位</span>30<span style="margin:0px;padding:0px;font-family:宋体;">家。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">生产工艺文献</span> : <span style="margin:0px;padding:0px;font-family:宋体;">以下按美国人提供的</span>“<span style="margin:0px;padding:0px;font-family:宋体;">共享</span>”<span style="margin:0px;padding:0px;font-family:宋体;">目录编排。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">BIOS 1149, 24.<span style="margin:0px;padding:0px;font-family:宋体;">（</span>=<span style="margin:0px;padding:0px;font-family:宋体;">胶卷</span>PB 80376<span style="margin:0px;padding:0px;font-family:宋体;">）</span> Acetyl-o-anisidine-4-sulphonylchloride.  <span style="margin:0px;padding:0px;font-family:宋体;">英国人译自德文。</span>    <span style="margin:0px;padding:0px;font-family:宋体;">抄录如下。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">反应式</span>: <span style="margin:0px;padding:0px;font-family:宋体;">本人有加注。译者未说明译自哪个德文原件。因为抄录原件，所以不能肯定是那个</span>PB<span style="margin:0px;padding:0px;font-family:宋体;">报告号。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-family:宋体;font-size:12px;"></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <img class="" data-copyright="0" data-ratio="0.29285714285714287" data-s="300,640" src="https://mmbiz.qpic.cn/mmbiz_png/HOvvD5XudaOibxJNicCIm3ASfbAlkwSYjzeqicxlWZImD2mKa7yyeJLjAqA6TicJ7KibB690IBMSY6XWZktmibgB2Z2w/640?wx_fmt=png" data-type="png" data-w="280" style="margin:0px;padding:0px;max-width:100%;height:auto !important;" /> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Outline: <br style="margin:0px;padding:0px;" /> <span style="margin:0px;padding:0px;font-family:宋体;"></span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Acet-o-anisidideis heated with chlorosulphonic acid, the product drowned into ice water and thesulphonchloride filtered.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Plant:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    1 Cast iron vessel of 2000 l. capacity with iron propeller agitator (65-70r.p.m.), heated with gas and with a water jacket.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">1  Measure vessel for chlorosulphonic acid.        1 Wood vat of 10000 l. capacity.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">1  C.I. tiled blow-egg of 8000 l. capacity.           1 Presses clothed with nitrated filter cloth.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Charge:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Acet-o-anisidide   425 kg. 100% (= 180 kg. NaNO2).      Chlorosulphonic acid   1800 kg.       Ice  5800 kg.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Process:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">The ironaulphonator is charged with 1800 kg. chlorosulphonic acid and theacet-o-anisidide charged in slowly with water cooling so that the temperaturedoes not rise above 300. When all has been charged the batch is held at 35-400for 10 hours. It isthen blown into a vat containing 1000 l. water and 1000 kg.ice; further ice is charged during the addition so that the temperature doesnot rise above 15<span style="margin:0px;padding:0px;font-family:宋体;">℃</span>. Total requirements of ice 5800 kg. When all has been charged theprecipitated sulphonchloride is filtered in a press, freed from as much motherliquor as possible, and washed almost free with cold water.    Yield = 84-86% theory.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">FIAT 1313, I,18-19.  <span style="margin:0px;padding:0px;font-family:宋体;">（</span>=<span style="margin:0px;padding:0px;font-family:宋体;">胶卷</span>PB 85172<span style="margin:0px;padding:0px;font-family:宋体;">）</span> N-Acetyl-4-methoxymetanilyl chloride  (Acetorthosinparachlorid)  I.G. Leverkusen.    </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">美国人译自德文。译文说明是</span>Bayer<span style="margin:0px;padding:0px;font-family:宋体;">公司生产工艺，但仍未说明译自哪个德文原件。</span>                      <span style="margin:0px;padding:0px;font-family:宋体;">抄录如下。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Apparatus:   To apparatus under3-Carboxy-4-hydrxoybenzenesulfone chloride, add 2 wood presses with nitratedfilter cloth in place of the nutsch.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Materials:  1 – 425 kg. acetorthoanisidine(acetorthosin).     2 – 1800 kg. chlorsulfonic acid.      3 – 5800 kg. ice.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">Prcedure:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    Charge cast iron kettle with (2) and slowlyshovel in (1), keeping temperature below 30<span style="margin:0px;padding:0px;font-family:宋体;">℃</span>. Then stir 10 hours at 35-40<span style="margin:0px;padding:0px;font-family:宋体;">℃</span>. Drown into</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">1000 l. waterand 1000 kg. ice, adding further ice to keep temperature below 15<span style="margin:0px;padding:0px;font-family:宋体;">℃</span>. Run to blow case and blow into press. Washwith cold water to remove as much free acid as possible,  Yield: 84-86% of theoretical.</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">日文译文。细田豊</span>  <span style="margin:0px;padding:0px;font-family:宋体;">《理论制造染料化学》</span> 1957<span style="margin:0px;padding:0px;font-family:宋体;">年。</span> p. 654.  <span style="margin:0px;padding:0px;font-family:宋体;">译自</span>PB 80376.                               <span style="margin:0px;padding:0px;font-family:宋体;">抄录如下。アセチル</span>-o-<span style="margin:0px;padding:0px;font-family:宋体;">アニシシ</span>”<span style="margin:0px;padding:0px;font-family:宋体;">ン</span>-4-<span style="margin:0px;padding:0px;font-family:宋体;">スルホニルクロリト</span>”:  <span style="margin:0px;padding:0px;font-family:宋体;">クロルスルホン酸</span> 1.8 t<span style="margin:0px;padding:0px;font-family:宋体;">にアストアニシシ</span>”<span style="margin:0px;padding:0px;font-family:宋体;">ン</span>100% 425 kg<span style="margin:0px;padding:0px;font-family:宋体;">を</span>300<span style="margin:0px;padding:0px;font-family:宋体;">以下て</span>”</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">加え，</span>35-400<span style="margin:0px;padding:0px;font-family:宋体;">に</span>1 h<span style="margin:0px;padding:0px;font-family:宋体;">保温，水</span> 1 t + <span style="margin:0px;padding:0px;font-family:宋体;">冰</span> 5.8 t<span style="margin:0px;padding:0px;font-family:宋体;">に</span>150<span style="margin:0px;padding:0px;font-family:宋体;">以下て</span>”<span style="margin:0px;padding:0px;font-family:宋体;">排出，滤洗する。收率</span> 84-86%<span style="margin:0px;padding:0px;font-family:宋体;">。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">中文译文。张澍声《精细化工中间体工业生产技术》</span> 1996<span style="margin:0px;padding:0px;font-family:宋体;">年。</span> P. 141. <span style="margin:0px;padding:0px;font-family:宋体;">译自</span>BIOS 1149.                       <span style="margin:0px;padding:0px;font-family:宋体;">抄录如下。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    <span style="margin:0px;padding:0px;font-family:宋体;">（一）氯磺化</span>:  <span style="margin:0px;padding:0px;font-family:宋体;">在</span>2000 L<span style="margin:0px;padding:0px;font-family:宋体;">铸铁磺化釜内加入</span>1800 kg<span style="margin:0px;padding:0px;font-family:宋体;">氯磺酸，在水冷却下缓缓加入</span>425 kg 100%<span style="margin:0px;padding:0px;font-family:宋体;">乙酰基邻氨基苯基醚（相当</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">于</span>180 kg NaNO2<span style="margin:0px;padding:0px;font-family:宋体;">），使温度不超过</span>30<span style="margin:0px;padding:0px;font-family:宋体;">℃</span>,<span style="margin:0px;padding:0px;font-family:宋体;">当所有物料加完后，反应物在</span>35-40<span style="margin:0px;padding:0px;font-family:宋体;">℃保持</span>10<span style="margin:0px;padding:0px;font-family:宋体;">小时，然后压人预先放有</span>1000 L<span style="margin:0px;padding:0px;font-family:宋体;">水和</span>1000</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">kg<span style="margin:0px;padding:0px;font-family:宋体;">冰的</span>10000 L<span style="margin:0px;padding:0px;font-family:宋体;">木槽中，在加料过程中还要加冰，使温度不超过</span>15<span style="margin:0px;padding:0px;font-family:宋体;">℃</span>,<span style="margin:0px;padding:0px;font-family:宋体;">总计需要</span>5800 kg<span style="margin:0px;padding:0px;font-family:宋体;">冰。当全部加完后，在压滤机上过滤沉</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">淀的磺酰氯，用冷水洗涤。收率</span> 84-86%<span style="margin:0px;padding:0px;font-family:宋体;">。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">PB 25623, 9-10.  Acetorthosinparachlorid. I.G. Leverkusen.  <span style="margin:0px;padding:0px;font-family:宋体;">德文生产工艺。</span>                                   <span style="margin:0px;padding:0px;font-family:宋体;">未抄录。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">PB 70422, 1914-1920.Acetortho-anisidine-para-chloride.  <span style="margin:0px;padding:0px;font-family:宋体;">德文生产工艺。</span> 1941<span style="margin:0px;padding:0px;font-family:宋体;">年</span>11<span style="margin:0px;padding:0px;font-family:宋体;">月</span>14<span style="margin:0px;padding:0px;font-family:宋体;">日。</span>                  <span style="margin:0px;padding:0px;font-family:宋体;">未抄录。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">PB 74026, 2364.  Acetirthosinparachloride.  <span style="margin:0px;padding:0px;font-family:宋体;">德文生产工艺摘要。</span>                                            <span style="margin:0px;padding:0px;font-family:宋体;">未抄录。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">国内研究动态</span> :</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">穆振义</span>  <span style="margin:0px;padding:0px;font-family:宋体;">（大工）猩红</span>LG<span style="margin:0px;padding:0px;font-family:宋体;">及</span>GTR<span style="margin:0px;padding:0px;font-family:宋体;">色基的试制。</span> [J]  <span style="margin:0px;padding:0px;font-family:宋体;">有机化学工业技术报导</span>, 1959, 11, 50-52.                   <span style="margin:0px;padding:0px;font-family:宋体;">摘录如下。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">合成方法的讨论</span>:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    <span style="margin:0px;padding:0px;font-family:宋体;">我们合成是参考了</span>BIOS 1149<span style="margin:0px;padding:0px;font-family:宋体;">的资料，认为这个资料还是可靠的，但是在资料中未提到产品分析及鉴定，我们实验中对每步</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-family:宋体;font-size:12px;">反应都有所改变，也摸索到了一些经验。</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">1.  <span style="margin:0px;padding:0px;font-family:宋体;">氯磺化</span>:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    <span style="margin:0px;padding:0px;font-family:宋体;">通过实验我们认为：小量的试验不一定需要</span>BIOS<span style="margin:0px;padding:0px;font-family:宋体;">介绍的那样</span>10<span style="margin:0px;padding:0px;font-family:宋体;">小时，我们用</span>5<span style="margin:0px;padding:0px;font-family:宋体;">小时，</span>2.5<span style="margin:0px;padding:0px;font-family:宋体;">小时试验的结果，产量质量也是</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">保证的，产率也比</span>BIOS<span style="margin:0px;padding:0px;font-family:宋体;">有所提高。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    <span style="margin:0px;padding:0px;font-family:宋体;">据文献记载，工业品磺酰氯的熔点</span>146-1470<span style="margin:0px;padding:0px;font-family:宋体;">。但我们实验开始时用分析纯度为</span>96%<span style="margin:0px;padding:0px;font-family:宋体;">的产品测定也是达不到，后来把经过充</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-family:宋体;font-size:12px;">分水洗到无酸性的产品用来测定熔点达到了文献上的记载，同时通过实验也发现对产品的久存也有很大好处，特别是对下步反</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-family:宋体;font-size:12px;">应，亚磺酸的中性介质还原更有其特殊的意义。</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;">    <span style="margin:0px;padding:0px;font-family:宋体;">产品的分析我们试用了乙酰基水解。用</span>NaNO2<span style="margin:0px;padding:0px;font-family:宋体;">滴定的方法，经过多次分析和物料的衡算，证明分析方法还是可靠的。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">无参考文献</span>;</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">加注</span>:</span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">抄录国内研究动态，说明国内研究文献是按英国人的英文译文</span>BIOS 1149,24.<span style="margin:0px;padding:0px;font-family:宋体;">开始的。问题是当时已进口有</span>BIOS<span style="margin:0px;padding:0px;font-family:宋体;">和</span>FIAT<span style="margin:0px;padding:0px;font-family:宋体;">的英文资料，也同时进口有胶卷，即</span>PB<span style="margin:0px;padding:0px;font-family:宋体;">报告原件，说明国内也未看德文原件。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">本文与</span>C.I. <span style="margin:0px;padding:0px;font-family:宋体;">冰染重氮组分</span>42 <span style="margin:0px;padding:0px;font-family:宋体;">的中间体有重复，这里是单列，所以增加了内容。以上仅供参考。</span></span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"> </span> <br /> <p style="margin-top:0px;margin-bottom:0px;padding:0px;clear:both;font-family:"font-size:medium;white-space:normal;"> <span style="margin:0px;padding:0px;font-size:12px;"><span style="margin:0px;padding:0px;font-family:宋体;">陈忠源</span>  2018<span style="margin:0px;padding:0px;font-family:宋体;">年</span>7<span style="margin:0px;padding:0px;font-family:宋体;">月</span>8<span style="margin:0px;padding:0px;font-family:宋体;">日星期日。</span></span> <br /><br /><br />本文地址：<a href="http://www.陈忠源化学文库.cn/Article.asp?ID=10000742" target="_blank">http://www.陈忠源化学文库.cn/Article.asp?ID=10000742</a>   填写邮件内容   邮件签名     填写邮件签名 发信地址     填写发信人的电子邮箱 　验证码     填写验证码，单击即可刷新验证码   发送协议 ·欢迎使用本站在线文章发送系统。 ·不得使用本站在线发送邮件系统发送垃圾邮件、广告邮件。 ·如果收信人地址或其服务器出现错误，可能无法成功发送。 ·如果有什么问题，或者意见建议，请联系[网站管理员]。

陈忠源化学文库 本站使用网站系统         苏ICP备10009270号-1          版权所有：无锡明辉国际贸易有限公司